余甘子固定化单宁的制备及其对Ge(Ⅳ)、Ga(Ⅲ)及In(Ⅲ)的吸附特性研究

doi:10.3969/j.issn.0253-2417.2020.01.013

Abstract

Abstract:

A solid adsorption materials, Phyllanthus emblica immobilized-tannin(PEIT), was prepared based on glutaral as crosslinking agent and chitosan as polymer matrix. The structure and thermal properties of PEIT were characterized by using FT-IR, DSC and TG. The results showed that P. emblica tannins were immobilized on chitosan by glutaral crosslinking. The optimum conditions for preparing PEIT were found as follows:the mass ratio of glutaral to tannin 1:4, the mass ratio of chitosan to tannin 1.5:1, the initial pH value of the reaction solution 4.0, and 55℃ for 3.0 h. The result of using PEIT to adsorb metal ions showed that PEIT has good adsorption effection on Ge (Ⅳ), Ga (Ⅲ), In (Ⅲ). The PEIT demonstrated the maximum adsorption efficiency at pH 4.0 for In (Ⅲ) and pH 3.0 for Ge (Ⅳ) and Ga (Ⅲ). The adsorption for these three metal ions followed pseudo second-order kinetics, indicating the chemisorption nature. The adsorption process of PEIT to Ge(Ⅳ), Ga (Ⅲ), In (Ⅲ) was not sensitive to temperature, and the best adsorption temperature was 30℃. The adsorption isotherms all fitted well with the Langmuir model, PEIT was based on a monolayer adsorption onto homogenous surfaces by uniformly distributed adsorption sites, and the calculated maximum adsorption capacities were 67.65, 70.00 and 54.10 mg/g for Ga(Ⅲ), In(Ⅲ), Ge(Ⅳ), respectively.

Key words: Phyllanthus emblica, immobilized-tannin, chitosan, adsorption, dissipated metal

CLC Number:

TQ35
S713

Cheng HUANG,Kun LI,Wenwen ZHANG,Hong ZHANG,Yanlin SUN,Yiwen LIU. Preparation of Phyllanthus emblica Immobilized-tannin and Its Adsorption Characteristics to Ge (Ⅳ), Ga (Ⅲ) and In (Ⅲ)[J]. Chemistry and Industry of Forest Products, 2020, 40(1): 91-100.

Figures/Tables 13

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References 25

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项目 items		余甘子单宁转化率/% tannin conversion	PEIT中的单宁质量分数/% tannin contents in PEIT
m(戊二醛):m(余甘子单宁) mass ratio of glutaral to tannin	1:2	96.95±0.36	39.26±0.36
	1:4	96.95±0.24	43.68±0.26
	1:8	95.85±0.30	46.00±0.32
	1:16	94.64±0.10	47.11±0.10
	1:32	88.96±0.33	46.31±0.35
m(壳聚糖):m(余甘子单宁) mass ratio of chitosan to tannin	0.5:1	93.34±0.28	55.45±0.30
	1:1	96.34±0.32	43.53±0.32
	1.5:1	97.45±0.20	35.77±0.19
	2:1	95.62±0.15	29.82±0.19
	2.5:1	93.77±0.12	25.43±0.12
初始pH值 initial pH value	2	92.55±0.26	34.59±0.26
	3	95.22±0.17	35.24±0.18
	4	97.45±0.20	35.77±0.20
	5	92.43±0.49	34.56±0.45
	6	88.25±0.36	33.52±0.36

项目 items		余甘子固定化单宁对金属离子的吸附量PEIT adsorption effect on metal ions/(mg·g^-1)
项目 items		Co²⁺	Mn²⁺	Ni ²⁺	Cu ²⁺	Zn²⁺	Cd²⁺	Pb²⁺	Ba ²⁺
m(戊二醛):m(余甘子) mass ratio of glutaral to tannin	1:2	1.73	3.22	2.72	9.41	1.45	4.43	16.81	3.245
	1:4	0.86	2.02	0.92	14.17	1.51	2.92	16.72	1.34
	1:8	2.45	2.38	2.39	9.45	0.39	2.77	11.12	3.81
	1:16	2.31	4.94	2.65	21.82	2.49	2.21	26.21	3.29
	1:32	2.15	1.97	2.12	21.27	2.88	1.93	24.71	4.54
m(壳聚糖):m(余甘子) mass ratio of chitosan to tannin	0.5:1	3.26	1.55	1.94	8.91	0.93	1.81	10.21	3.05
	1:1	1.41	3.09	3.38	8.80	2.25	2.66	14.90	3.42
	1.5:1	2.24	3.55	4.15	13.89	2.75	4.38	10.64	2.31
	2:1	4.68	4.69	2.39	16.31	3.25	3.53	17.59	1.06
	2.5:1	4.23	3.93	2.88	18.82	2.37	2.09	17.76	1.36
初始pH值 initial pH value	2	1.47	1.51	2.65	14.58	2.61	4.400	4.11	2.93
	3	1.72	2.43	2.41	6.54	0.76	2.14	3.02	4.33
	4	2.37	2.83	2.32	4.25	1.13	3.96	2.49	3.80
	5	2.47	2.04	3.90	19.17	2.10	1.51	21.15	3.65
	6	2.04	2.95	3.31	22.97	3.00	5.33	15.63	3.35

项目 items		余甘子固定化单宁对金属离子的吸附量PEIT adsorption effect on metal ions/(mg·g^-1)
项目 items	Al³⁺	Fe³⁺	Cr³⁺	Ga³⁺	In³⁺	Ge ⁴⁺
m(戊二醛):m(余甘子) mass ratio of glutaral to tannin	1:2	35.02	29.99	40.24	49.86	42.65	51.65
	1:4	27.41	51.47	32.09	49.99	53.38	53.80
	1:8	27.12	19.04	31.07	32.75	37.04	34.48
	1:16	31.17	16.35	34.14	33.76	36.61	36.24
	1:32	41.67	34.70	46.73	47.57	50.92	51.99
m(壳聚糖):m(余甘子) mass ratio of chitosan to tannin	0.5:1	25.02	35.88	28.38	33.80	30.35	32.82
	1:1	24.37	32.83	28.52	29.21	29.86	30.54
	1.5:1	21.95	28.79	26.37	38.28	39.20	40.94
	2:1	26.67	33.41	30.15	30.46	30.78	32.02
	2.5:1	29.94	34.11	33.46	32.98	32.71	34.50
初始pH值 initial pH value	2	17.28	28.99	17.56	18.94	18.43	21.21
	3	17.81	28.04	21.57	23.73	23.22	26.10
	4	21.10	41.04	25.86	28.85	27.42	29.87
	5	26.72	31.05	27.45	28.47	25.96	29.98
	6	29.51	27.90	31.03	32.59	29.79	33.39

金属离子metal ions	q_t/(mg·g^-1)	准一级动力学方程 pesado first-order			准二级动力学方程 pesudo second-order			颗粒内部扩散方程 intraparticle diffusion
金属离子metal ions	q_t/(mg·g^-1)	R²	k₁/h^-1	q_e/(mg·g^-1)	R²	k₂/(g·mg^-1·h^-1)	q_e/(mg·g^-1)	R²	k_id/(mg·g^-1·h^0.5)	c
Ga³⁺	43.884	0.200	0.042	3.284	0.99986	0.267	43.516	0.499	2.323	35.281
In³⁺	56.391	0.235	0.048	3.449	0.99985	0.150	56.433	0.527	2.794	46.064
Ge⁴⁺	37.967	0.079	0.078	1.472	0.9999	-2.467	37.439	0.284	0.797	35.006

金属离子 metal ions	Langmuir				Freundlich
金属离子 metal ions	q_e，exp/(mg· g^-1)	R²	q_m/(mg·g^-1)	K_L/(L·g^-1)	R²	K_F/(mg·g^-1)	n
Ga(Ⅲ)	67.6539	0.9867	72.4113	0.0364	0.6567	10.7117	2.9445
In(Ⅲ)	70.0020	0.9752	76.4526	0.0346	0.6926	9.3272	2.5993
Ge(Ⅳ)	54.1074	0.9903	54.6747	0.0770	0.6149	12.5232	3.5585

Preparation of Phyllanthus emblica Immobilized-tannin and Its Adsorption Characteristics to Ge (Ⅳ), Ga (Ⅲ) and In (Ⅲ)

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