合成莰烯衍生醛、酮、硫酯类化合物的新方法

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›› 2002, Vol. 22 ›› Issue (1): 35-37.

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A NEW ROUTE OF SYNTHESIZING CAMPHENE DERIVATIVE COMPOUNDS--ALDEHYDE,KETONES AND THIOESTERS

ZHONG Ping, HUANG Nan-ping

Department of Chemistry, Wenzhou Normal College, Wenzhou 325027, China

Received:2001-02-12 Revised:1900-01-01 Online:2002-03-30 Published:2002-03-30

Abstract

Abstract: Camphene reacted with Cp₂Zr(H)Cl(Cp=η⁵-C₅H₅ )and CO to form acylzirconocene chloride derivative,which was trapped with water,aryl halides and arylsulfenyl chlorides to give aldehyde,ketones and thioesters respectively.Camphene reacted with Cp₂Zr(H)Cl in THF to give organozirconium(Ⅳ)complex,which was trapped with benzoyl chloride in the presence of CuI to give ketone 8a.

Key words: camphene, hydrozirconation, aldehyde, ketone, thioester

CLC Number:

ZHONG Ping;HUANG Nan-ping . A NEW ROUTE OF SYNTHESIZING CAMPHENE DERIVATIVE COMPOUNDS--ALDEHYDE,KETONES AND THIOESTERS[J]. , 2002, 22(1): 35-37.

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A NEW ROUTE OF SYNTHESIZING CAMPHENE DERIVATIVE COMPOUNDS--ALDEHYDE,KETONES AND THIOESTERS

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