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林产化学与工业

林产化学与工业 ›› 2014, Vol. 34 ›› Issue (2): 45-50.doi: 10.3969/j.issn.0253-2417.2014.02.008

• 研究报告 • 上一篇    下一篇

锥形量热法研究APP/5A分子筛对木材的阻燃抑烟作用

陈旬1, 袁利萍1, 胡云楚1 2, 田梁材2, 王洁2, 夏燎原1   

  1. 1. 中南林业科技大学 材料与工程学院, 湖南 长沙 410004;
    2. 中南林业科技大学 理学院, 湖南 长沙 410004
  • 收稿日期:2013-04-09 出版日期:2014-04-25 发布日期:2014-04-26
  • 通讯作者: 胡云楚（1960-），男，湖南湘潭人，教授，博士，博士生导师，主要从事材料化学和阻燃材料方面的研究；E-mail：hucsfu@163.com。 E-mail:hucsfu@163.com
  • 作者简介:陈旬（1988-），女，湖南岳阳人，硕士生，主要从事阻燃剂及阻燃材料方面的研究
  • 基金资助:
    国家自然科学基金资助项目（31170521）；湖南省研究生科研创新项目（CX2012B325）；中南林业科技大学研究生科技创新基金项目（CX2012B05）

Effects of the Molecular Sieve 5A and APP on the Flame Retardance and Smoke Suppression in Wood by Cone Calorimeter

CHEN Xun1, YUAN Li-ping1, HU Yun-chu1 2, TIAN Liang-cai2, WANG Jie2, XIA Liao-yuan1   

  1. 1. College of Material Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China;
    2. College of science, Central South University of Forestry and Technology, Changsha 410004, China
  • Received:2013-04-09 Online:2014-04-25 Published:2014-04-26

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摘要： 采用锥形量热法研究了5A分子筛与聚磷酸铵（APP）在木材燃烧过程中的阻燃作用和烟气吸附调控作用。结果表明：APP单独使用时总热释放量（THR）降低47.56%，但是平均CO产率增加185.71%；5A分子筛单独使用时阻燃效果远远不如APP，THR只降低了16.86%；5A分子筛与APP复合使用THR降低34.23%，总烟释放量（TSP）降低了76.07%，平均CO产率降低了68.33%。5A分子筛能将木材热解产生的以CO为代表的有毒气体催化转化为CO2，从而减少了毒气的产生和释放。5A分子筛与APP联用，在高效阻燃的同时减少烟雾毒气释放，降低了火灾危害。

关键词: 5A分子筛, 木材阻燃, 抑烟减毒

Abstract: The effect of molecular sieve 5A and ammonium polyphosphate (APP) on the flame retardance and smoking-gas absorption in wood during the combustion process was investigated by cone calorimeter. The results showed that when APP was used as sole flame retardant, the total heat release (THR) reduced by 47.56% while mean yield of CO (mean-COY) increased by 185.71%. The application of molecular sieve 5A was found to have an inferior flame retardant efficiency. THR decreased by 16.86% through it. However, when 5A molecular sieve and APP was combined and used as flame retardant for wood, THR, total smoke production (TSP) and mean-COY reduced by 34.23%, 76.07% and 68.33%, respectively. CO, a representative toxic, was converted into CO2 by the use of 5A molecular sieve as catalyst. Thus the generation and release of toxic gas reduced. In short, high efficiency of flame retardance and smoke suppression in wood can be achieved when the flame retardants of 5A molecular sieve and APP were coused together. Thus the casualties in the fire were reduced.

Key words: 5A molecular sieve, fire resistance of wood, smoke inhibition and conversion

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