萜类植物源除草活性物开发及应用研究进展

doi:10.3969/j.issn.0253-2417.2019.02.001

林产化学与工业 ›› 2019, Vol. 39 ›› Issue (2): 1-8.doi: 10.3969/j.issn.0253-2417.2019.02.001

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萜类植物源除草活性物开发及应用研究进展

徐士超^1,^2,³,曾小静^1,²,董欢欢^1,²,赵振东^1,^2,^3,*()

1. 中国林业科学研究院林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业局林产化学工程重点开放性实验室; 江苏省生物质能源与材料重点实验室, 江苏南京 210042
2. 南京林业大学江苏省林业资源高效加工利用协同创新中心, 江苏南京 210037
3. 中国林业科学研究院林业新技术研究所, 北京 100091

收稿日期:2018-06-15 出版日期:2019-04-25 发布日期:2019-05-08
通讯作者: 赵振东 E-mail:zdzhao@189.cn
作者简介:徐士超(1985—)，男，山东临沂人，副研究员，主要从事萜类化学、绿色化学、天然产物化学等方面的研究与利用
基金资助:
中国林科院中央级公益性科研院所基本科研业务费专项资金项目(CAFYBB2018SZ012);国家自然科学基金青年基金项目(31600466)

Research Progress in Development and Application of Terpenoid Botanical Herbicides

Shichao XU^1,^2,³,Xiaojing ZENG^1,²,Huanhuan DONG^1,²,Zhendong ZHAO^1,^2,^3,*()

1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. of Forest Chemical Engineering, SFA; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
2. Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China
3. Research Institute of Forestry New Technology, CAF, Beijing 100091, China

Received:2018-06-15 Online:2019-04-25 Published:2019-05-08
Contact: Zhendong ZHAO E-mail:zdzhao@189.cn
Supported by:
中国林科院中央级公益性科研院所基本科研业务费专项资金项目(CAFYBB2018SZ012);国家自然科学基金青年基金项目(31600466)

摘要/Abstract

摘要：

综述了近年来国内外萜类化合物及其衍生物在除草应用领域的研究进展，从天然萜类精油、萜类化合物单组分以及萜类衍生物(包括席夫碱衍生物、硫脲衍生物、酰胺衍生物、含氧衍生物及其他)除草应用的角度出发，对近年来萜类植物源除草剂的开发和应用进行了系统的归纳和总结，着重介绍了松节油单萜衍生物的合成及其除草应用的研究现状及成果，展望了萜类植物源除草剂的发展方向及应用前景。

关键词: 植物精油, 萜类化合物, 改性合成, 植物源除草剂

Abstract:

In this paper reviewed the recent research progress of terpene compounds and their derivatives in the application field of herbicides were reviewed. From the perspective of herbicidal application of natural terpenoid essential oil, pure terpenoid compounds and terpenoid derivatives, the exploration and application of terpene-based botanical herbicides in recent years were systematically induced and summarized. On this basis, the research status and achievements for the synthesis and herbicidal application of turpentine monoterpene derivatives were focused. The development direction and application prospect of terpene type botanical herbicides were also forecasted.

Key words: plant essential oil, terpenoids, modified synthesis, botanical herbicides

中图分类号:

TQ35

徐士超,曾小静,董欢欢,赵振东. 萜类植物源除草活性物开发及应用研究进展[J]. 林产化学与工业, 2019, 39(2): 1-8.

Shichao XU,Xiaojing ZENG,Huanhuan DONG,Zhendong ZHAO. Research Progress in Development and Application of Terpenoid Botanical Herbicides[J]. Chemistry and Industry of Forest Products, 2019, 39(2): 1-8.

图/表 8

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化合物名称 compounds	结构式 structural formula	IC₅₀/(mmol·L^-1)
化合物名称 compounds	结构式 structural formula	根 root	茎 stem
1, 8-萜二醇 terpin monohydrate		>20	>20^[37]
对孟烷-1, 8-二胺 p-menthane-1, 8-diamine		0.96	2.68^{[35, 5]}
3-对孟烯-1-胺 3-p-menthene-1-amine		0.24	0.46^[34]
对孟烷-1, 8-二酰胺 p-menthane-1, 8-diamide		10.33	14.40^[6]
草甘膦 glyphosate	—	0.14	0.41^{[34, 5]}
3-对孟烯-1-酰胺 3-p-menthene-1-amide		0.56	0.47^[37]
对孟烷-1, 8-二席夫碱^a p-menthane-1, 8- Schiff base		< 0.14	< 0.41^{[5, 35]}
3-对孟烯-1-席夫碱^b 3-p-menthene-1- Schiff base		< 0.14	< 0.41^[34]
N-乙酰基-1, 2-环氮对孟烷 N-acetyl-1, 2-azacyclo-p-menthane		0.56	0.68^[6]
敌草隆 diuron	—	6.68	8.73^[6]

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萜类植物源除草活性物开发及应用研究进展

Research Progress in Development and Application of Terpenoid Botanical Herbicides

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