桉木化学机械浆废水好氧生物抑制特性分析及降解规律研究

doi:10.3969/j.issn.0253-2417.2024.01.005

林产化学与工业 ›› 2024, Vol. 44 ›› Issue (1): 33-40.doi: 10.3969/j.issn.0253-2417.2024.01.005

桉木化学机械浆废水好氧生物抑制特性分析及降解规律研究

丁来保(), 田庆文, 杨然, 朱津苇, 郭奇, 房桂干()

中国林业科学研究院林产化学工业研究所; 江苏省生物质能源与材料重点实验室; 国家林业和草原局林产化学工程重点实验室; 林木生物质低碳高效利用国家工程研究中心; 江苏省林业资源高效加工利用协同创新中心, 江苏南京 210042

收稿日期:2023-10-20 出版日期:2024-02-28 发布日期:2024-02-23
通讯作者: 房桂干 E-mail:dingyua2019@163.com;ppfangguigan@163.com
作者简介:房桂干, 研究员, 博士生导师, 主要从事制浆造纸、环境保护及生物质高值化利用技术等方面的研究; E-mail: ppfangguigan@163.com
丁来保(1974—)，男，安徽无为人，副研究员，博士，主要从事水污染控制技术研究；E-mail: dingyua2019@163.com
基金资助:
江苏省生物质能源与材料重点实验室重点项目(JSBEM-S-202207)

Analysis of Aerobic Biological Inhibition Characteristics and Degradation Law of Eucalyptus Chemical Mechanical Pulp Wastewater

Laibao DING(), Qingwen TIAN, Ran YANG, Jinwei ZHU, Qi GUO, Guigan FANG()

Institute of Chemical Industry of Forest Products, CAF; Key Lab. of Biomass Energy and Material, Jiangsu Province; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass; Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing 210042, China

Received:2023-10-20 Online:2024-02-28 Published:2024-02-23
Contact: Guigan FANG E-mail:dingyua2019@163.com;ppfangguigan@163.com

摘要/Abstract

摘要：

采用GC-MS方法分析了桉木化学机械浆废水厌氧处理和好氧处理出水的有机物成分及含量，统计了好氧处理前后废水中碳原子数的分析情况，分析了废水中主要的生物难降解组分及降解规律。研究结果表明：经厌氧和好氧处理后残余的主要有机污染物为芳樟醇(C10，21.21%)、对叔丁基苯乙酸甲酯(C13，21.39%)、二氢月桂烯醇(C10，8.90%)、铃兰醛(C14，6.16%)和香茅醇(C10，4.76%)等，主要为含苯环有机物和抑菌成分，具有生物难降解性和抑菌性，宏观表现为生物处理去除率较低。好氧处理前后，废水中醇类物质质量分数从19.32%上升至51.71%，醛类物质质量分数从3.68%上升至13.35%，酯类物质质量分数从29.75%降至28.32%，含苯环有机物质量分数从32.70%上升至61.06%，说明其他有机物获得比含苯环有机物更大幅度的降解。建议通过解毒预处理和生物强化提高微生物活性等途径改善生物处理效果，减轻后续深度处理的难度，降低综合处理成本，实现低成本达标排放。

关键词: 桉木化机浆废水, 生物处理, 生物抑制, 降解规律, 脱毒解毒

Abstract:

In this paper, the composition and content of organic matter in the effluent of anaerobic treatment and aerobic treatment of eucalyptus chemical mechanical pulp wastewater were analyzed by GC-MS method. The analysis of number of carbon atoms in the wastewater before and after aerobic treatment was counted, and the main bio-refractory components and degradation rules in the wastewater were analyzed. The results showed that the main residual organic pollutants after anaerobic and aerobic treatment were linalool (C10, 21.21%), methyl p-tert-butyl phenylacetate (C13, 21.39%), dihydromyrcenol (C10, 8.90%), lilial (C14, 6.16%) and citronellol (C10, 4.76%), etc, mainly containing benzene ring organic matter and bacteriostatic components, with biological refractory degradation and bacteriostatic properties. The macroscopic performance was that the removal rate of biological treatment was low. Before and after aerobic treatment, the mass fraction of alcohols in wastewater increased from 19.32% to 51.71%, the mass fraction of aldehydes increased from 3.68% to 13.35%, the mass fraction of esters decreased from 29.75% to 28.32%, and the mass fraction of benzene-containing organics increased from 32.70% to 61.06%, indicating that other organics were degraded more greatly than benzene-containing organics. It was recommended to improve the biological treatment effect by detoxification pretreatment and bioaugmentation to improve microbial activity, reduce the difficulty of subsequent deep treatment, reduce the cost of comprehensive treatment, and achieve low-cost discharge.

Key words: eucalyptus chemi-mechanical pulp wastewater, biological treatment, biological inhibition, degradation law, detoxification

中图分类号:

TQ35

丁来保, 田庆文, 杨然, 朱津苇, 郭奇, 房桂干. 桉木化学机械浆废水好氧生物抑制特性分析及降解规律研究[J]. 林产化学与工业, 2024, 44(1): 33-40.

Laibao DING, Qingwen TIAN, Ran YANG, Jinwei ZHU, Qi GUO, Guigan FANG. Analysis of Aerobic Biological Inhibition Characteristics and Degradation Law of Eucalyptus Chemical Mechanical Pulp Wastewater[J]. Chemistry and Industry of Forest Products, 2024, 44(1): 33-40.

图/表 4

表1

厌氧出水中检测出的有机物及其含量"

序号 No.	保留时间/min retention time	化合物 compound	分子式 molecular formula	相对峰面积/% relative peak area
1	3.966	丁酸butanoic acid	C₄H₈O₂	0.51
2	4.760	1-氨基-1-环戊醇cyclopentanemethanol, 1-amino	C₆H₁₃NO	0.35
3	5.406	戊酸pentanoic acid	C₅H₁₀O₂	0.53
4	6.889	己酸hexanoic acid	C₆H₁₂O₂	0.24
5	7.122	八甲基环四硅氧烷cyclotetrasiloxane, octamethyl-	C₈H₂₄O₄Si₄	1.84
6	7.708	D-柠檬烯D-limonene	C₁₀H₁₆	8.38
7	7.938	苯甲醇benzyl alcohol	C₇H₈O	0.63
8	8.360	二氢月桂烯醇7-octen-2-ol, 2, 6-dimethyl-	C₁₀H₂₀O	2.91
9	8.474	对甲苯酚p-cresol	C₇H₈O	1.66
10	8.803	芳樟醇linalool	C₁₀H₁₈O	7.72
11	9.047	α-乙基己酸hexanoic acid, 2-ethyl-	C₈H₁₆O₂	0.16
12	9.099	葑醇fenchol	C₁₀H₁₈O	0.59
13	9.311	2, 4-二甲基-2, 4-庚二烯醛2, 4-heptadienal, 2, 4-dimethyl-	C₉H₁₄O	0.30
14	9.551	十甲基环五硅氧烷cyclopentasiloxane, decamethyl-	C₁₀H₃₀O₅Si₅	2.94
15	10.243	1-苯乙酸乙酯1-phenylethyl acetate	C₁₀H₁₂O₂	1.14
16	10.338	N-乙酰-4-甲氧基苯丙胺4-methoxyamphetamine, N-acetyl	C₁₂H₁₇NO₂	0.32
17	10.737	香茅醇citronellol	C₁₀H₂₀O	4.72
18	11.248	1-甲基-4-(1-甲基乙烯基)环己醇1-methyl-4-(1-methylethenyl)-cyclohexanol	C₁₀H₁₈O	0.17
19	11.356	甲酸松油酯terpinyl formate	C₁₁H₁₈O₂	0.25
20	11.701	顺-2-(1, 1-二甲基乙基)环己醇乙酸酯(cyclohexanol, 2-(1, 1-dimethylethyl)-, acetate, cis-)	C₁₂H₂₂O₂	7.92
21	11.860	吲哚indole	C₈H₇N	0.18
22	12.016	十二甲基环六硅氧烷cyclohexasiloxane, dodecamethyl-	C₁₂H₃₆O₆Si₆	2.63
23	12.426	3-烯丙基过氧基-对烷p-menthane, 3-allylperoxy-	C₁₃H₂₄O₂	0.33
24	12.784	α, 2, 6, 6-四甲基-1-环己烯-1-甲醇1-cyclohexene-1-methanol, α, 2, 6, 6-tetramethyl-	C₁₁H₂₀O	0.16
25	13.399	α-柏木烯α-cedrene	C₁₅H₂₄	1.31
26	13.539	2-异丙基-5-甲基-9-亚甲基-双环[4.4.0]癸-1-烯bicyclo[4.4.0]dec-1-ene, 2-isopropyl-5-methyl-9- methylene-	C₁₅H₂₄	0.38
27	13.639	罗汉柏烯cis-thujopsene	C₁₅H₂₄	2.22
28	14.249	十四甲基环七硅氧烷cycloheptasiloxane, tetradecamethyl-	C₁₄H₄₂O₇Si₇	1.23
29	14.563	N- (2-氯乙氧基)羰基-异己酯- D-正亮氨酸D-norleucine, N-(2-chloroethoxy)carbonyl-, isohexyl ester	C₁₅H₂₈ClNO₄	1.21
30	14.753	2, 5-二甲基-苯丁酸benzenebutanoic acid, 2, 5-dimethyl-	C₁₂H₁₆O₂	0.39
31	15.173	白檀醇2-buten-1-ol, 2-ethyl-4-(2, 2, 3-trimethyl-3- cyclopenten-1-yl)-	C₁₄H₂₄O	0.55
32	15.536	邻苯二甲酸二乙酯diethyl phthalate	C₁₂H₁₄O₄	1.42
33	15.627	对叔丁基苯乙酸甲酯benzeneacetic acid, 4-(1, 1-dimethylethyl)-, methyl ester	C₁₃H₁₈O₂	15.59
34	15.779	1-(3, 6, 6-三甲基-1, 6, 7, 7a-四氢环戊并[c]吡喃-1-基)乙酮1-(3, 6, 6-trimethyl-1, 6, 7, 7a-tetrahydrocyclopenta[c]pyran-1-yl)ethanone	C₁₃H₁₈O₂	1.26
35	15.981	雪松醇cedrol	C₁₅H₂₆O	1.52
36	16.205	二氢茉莉酮酸甲酯methyl 2-(3-oxo-2-pentylcyclopentyl)acetate	C₁₃H₂₂O₃	1.19
37	16.241	十六甲基环八硅氧烷cyclooctasiloxane, hexadecamethyl-	C₁₆H₄₈O₈Si₈	0.83
38	16.509	水杨酸己酯n-hexyl salicylate	C₁₃H₁₈O₃	0.61
39	17.279	α-己基肉桂醛octanal, 2-(phenylmethylene)-	C₁₅H₂₀O	2.27
40	17.862	6-(1, 1-二甲基硫脲)-苯并噻唑-2(3H)-硫酮benzothiazole-2(3H)-thione, 6-(1, 1-dimethylthioureido)-	C₁₀H₁₁N₃S₃	0.53
41	17.980	十八甲基环壬硅氧烷cyclononasiloxane, octadecamethyl-	C₁₈H₅₄O₉Si₉	0.31
42	18.444	1, 3, 4, 6, 7, 8-六氢-4, 6, 6, 7, 8, 8-六甲基-环戊并[g]-2-苯并吡喃cyclopenta[g]-2-benzopyran, 1, 3, 4, 6, 7, 8-hexahydro- 4, 6, 6, 7, 8, 8-hexamethyl-	C₁₈H₂₆O	1.86
43	19.521	十六甲基八硅氧烷octasiloxane, hexadecamethyl-	C₁₆H₅₀O₇Si₈	0.18
44	19.715	富马酸, 2-辛基十三酸-2-炔-1-酯fumaric acid, 2-octyl tridec-2-yn-1-yl ester	C₂₅H₄₂O₄	0.16
45	20.439	1, 1-二氯-1-硅-2, 3-苯并-4, 5-噻吩并环戊二烯1, 1-dichloro-1-sila-2, 3-benzo-4, 5-thiophenocyclopentadiene	C₁₀H₆Cl₂SSi	12.90
46	20.654	甲基4-羟基硬脂酸酯octadecanoic acid, 4-hydroxy-, methyl ester	C₁₉H₃₈O₃	0.27
47	20.946	十六甲基七硅氧烷heptasiloxane, hexadecamethyl-	C₁₆H₄₈O₆Si₇	0.16
48	21.549	3-乙基-5-(2-乙基丁基)十八烷octadecane, 3-ethyl-5-(2-ethylbutyl)-	C₂₆H₅₄	0.40
49	21.962	(2, 2-二甲基-3-[3, 7, 12-三甲基-14-(1, 4, 4-三甲基环己-2-烯基)十四烷-3, 7, 11-三烯基]环氧乙烷(2, 2-dimethyl-3-[3, 7, 12-trimethyl-14-(1, 4, 4-trimethylcyclohex-2-enyl)tetradeca-3, 7, 11-trienyl]oxirane	C₃₀H₅₀O	0.30
50	22.411	溴代三十烷triacontane, 1-bromo-	C₃₀H₆₁Br	0.50
51	22.658	17α, 21β-28, 30-双降藿烷17α, 21β-28, 30-bisnorhopane	C₂₈H₄₈	0.18
52	22.926	2, 6-二羟基苯乙酮2, 6-dihydroxyacetophenone	C₁₄H₂₄O₃Si₂	0.28
53	23.239	1, 1, 3, 6-四甲基-2-(3, 6, 10, 13, 14-五甲基-3-乙基十五烷基)环己烷1, 1, 3, 6-tetramethyl-2-(3, 6, 10, 13, 14- pentamethyl-3-ethylpentadecyl)cyclohexane	C₃₂H₆₄	0.48
54	24.028	5β-胆甾烷- 3-酮-环1，2-乙二醛cholestan-3-one, cyclic 1, 2-ethanediyl aetal, (5β)-	C₂₉H₅₀O₂	0.50
55	24.798	1, 54-二溴-五十四烷tetrapentacontane, 1, 54-dibromo-	C₅₄H₁₀₈Br₂	0.46
56	25.566	5β-胆甾烷-3-酮乙缩醛5β-cholestan-3-one ethylene acetal	C₂₉H₅₀O₂	0.61
57	26.433	dasycarpidan-1-methanol, acetate	C₂₀H₂₆N₂O₂	0.62
58	27.451	4-乙酰氧亚氨基-6, 6-二甲基-3-甲基磺酰基-4，5，6，7-四氢苯并[c]噻吩-1-羧酸甲酯4-acetyloxyimino-6, 6-dimethyl-3-methylsulfanyl-4, 5, 6, 7-tetrahydro-benzo[c]thiophene-1-carboxylic acid methyl ester	C₁₅H₁₉NO₄S₂	0.58
59	28.623	2-(十六烷氧基)乙酯十八烷酸octadecanoic acid, 2-(hexadecyloxy)ethyl ester	C₃₆H₇₂O₃	0.16

表1

表2

好氧出水中有机物种类及其含量"

序号 No.	保留时间/min retention time	化合物 compound	分子式 molecular formula	相对峰面积/% relative peak area
1	7.125	八甲基环四硅氧烷cyclotetrasiloxane, octamethyl-	C₈H₂₄O₄Si₄	0.48
2	7.705	D-柠檬烯D-limonene	C₁₀H₁₆	1.83
3	7.830	苯甲醇benzyl alcohol	C₇H₈O	4.39
4	8.250	α-甲基-苯甲醇benzenemethanol, alpha-methyl-	C₈H₁₀O	1.19
5	8.383	二氢月桂烯醇7-octen-2-ol, 2, 6-dimethyl-	C₁₀H₂₀O	8.90
6	8.863	芳樟醇linalool	C₁₀H₁₈O	21.21
7	9.315	二氢芳樟醇1, 2-dihydrolinalool	C₁₀H₂₀O	0.52
8	9.554	十甲基环五硅氧烷cyclopentasiloxane, decamethyl-	C₁₀H₃₀O₅Si₅	1.01
9	9.618	香茅醛citronellal	C₁₀H₁₈O	2.31
10	9.961	2-叔丁基环己醇cyclohexanol, 2-(1, 1-dimethylethyl)-	C₁₀H₂₀O	4.70
11	10.045	2-叔丁基环己醇cyclohexanol, 2-(1, 1-dimethylethyl)-	C₁₀H₂₀O	1.08
12	10.240	α-松油醇alpha-terpineol	C₁₀H₁₈O	0.52
13	10.337	4-烯丙基苯甲醚estragole	C₁₀H₁₂O	0.33
14	10.724	香茅醇citronellol	C₁₀H₂₀O	4.76
15	10.936	马鞭草烯醇trans-verbenol	C₁₀H₁₆O	2.13
16	11.096	橙花醇cis-3, 7-dimethyl-2, 6-octadien-1-ol	C₁₀H₁₈O	0.39
17	11.345	柠檬醛citral	C₁₀H₁₆O	2.29
18	11.704	顺-2-(1, 1-二甲基乙基)环己醇乙酸酯cyclohexanol, 2-(1, 1-dimethylethyl)-, acetate, cis-	C₁₂H₂₂O₂	3.06
19	12.014	十二甲基环六硅氧烷cyclohexasiloxane, dodecamethyl-	C₁₂H₃₆O₆Si₆	0.77
20	13.406	α-柏木烯(-)-alpha-Cedrene	C₁₅H₂₄	0.23
21	13.639	罗汉柏烯cis-Thujopsene	C₁₅H₂₄	0.32
22	14.250	十四甲基环七硅氧烷cycloheptasiloxane, etradecamethyl-	C₁₄H₄₂O₇Si₇	0.29
23	14.492	2, 2, 2-三氯-1-苯基乙醇2, 2, 2-trichloro-1-phenylethanol	C₈H₇Cl₃O	1.34
24	14.756	铃兰醛lilial	C₁₄H₂₀O	6.16
25	15.231	5, 9-二甲基三环[6.3.0.0(1, 5)]十一烷-4-酮tricyclo[6.3.0.0(1, 5)]undecan-4-one, 5, 9-dimethyl-	C₁₃H₂₀O	0.31
26	15.601	对叔丁基苯乙酸甲酯4-tert phenylacetate	C₁₃H₁₈O₂	21.39
27	15.782	柏木脑cedrol	C₁₅H₂₆O	0.58
28	16.211	二氢茉莉酮酸甲酯cyclopentaneacetic acid, 3-oxo-2-pentyl-, methyl ester	C₁₃H₂₂O₃	3.21
29	16.505	水杨酸正己酯n-hexyl salicylate	C₁₃H₁₈O₃	0.66
30	16.563	2-甲基-3-[4-叔丁基]苯基丙酸propanoic acid, 2-methyl-3-[4-t-butyl]phenyl-	C₁₄H₂₀O₂	0.46
31	17.280	α-己基肉桂醛octanal, 2-(phenylmethylene)-	C₁₅H₂₀O	2.59
32	18.444	1, 3, 4, 6, 7, 8-六氢-4, 6, 6, 7, 8, 8-六甲基-环戊并[g]-2-苯并吡喃cyclopenta[g]-2-benzopyran, 1, 3, 4, 6, 7, 8-hexahydro- 4, 6, 6, 7, 8, 8-hexamethyl-	C₁₈H₂₆O	0.59

表2

图1

图2

参考文献 23

1	冉淼, 丁来保, 房桂干, 等. 化学机械浆废水处理技术现状与发展[J]. 中国造纸, 2021, 40 (7): 33- 39.
	RAN M , DING L B , FANG G G , et al. Progress on treatment technique of chemical mechanical pulp wastewater[J]. China Pulp & Paper, 2021, 40 (7): 33- 39.
2	张达俊. 广西的桉树及制浆造纸[J]. 国际造纸, 2000, 19 (5): 44- 50.
	ZHANG D J . Eucalyptus and pulping and papermaking in Guangxi[J]. World Pulp and Paper, 2000, 19 (5): 44- 50.
3	张峰, 毕良武, 赵振东. 樟树植物资源分布及化学成分研究进展[J]. 天然产物研究与开发, 2017, 29 (3): 517- 531.
	ZHANG F , BI L W , ZHAO Z D . Review on plant resources and chemical composition of camphor tree[J]. Natural Product Research and Development, 2017, 29 (3): 517- 531.
4	MITHOFER A , BLOAND W . Plant defense against herbivores: Chemical aspects[J]. Annual Review of Plant Biology, 2012, 63 (1): 431- 450. doi: 10.1146/annurev-arplant-042110-103854
5	SEYBOLD S J , HUBER D , LEE J . Pine monoterpenes and pine bark beetles: A marriage of convenience for defense and chemical communication[J]. Phytochemical Review, 2006, 5 (1): 143- 178. doi: 10.1007/s11101-006-9002-8
6	LOIVAMAKI M , MUMM R , DICKE M , et al. Isoprene interferes with the attraction of body-guards by herbaceous plants[J]. Proceedings of the National Academy of Sciences of the United States of America, 2008, 105 (45): 17430- 17435.
7	赵宇宁, 张皓冰. 桉树提取物及其化学成分的抗原虫作用[J]. 中国寄生虫学与寄生虫病杂志, 2016, 34 (2): 171- 178.
	ZHANG Y N , ZHANG H B . Antiprotozoal activities of eucalyptus extracts and their chemical components[J]. Chinese Journal of Parasitology and Parasitic Diseases, 2016, 34 (2): 171- 178.
8	HUANG Z H , QIN X , ZHU T , et al. Developing an efficient processing system treatment for the high concentration of eucalyptus chemical mechanical pulp wastewater[J]. Molecules, 2022, 27 (18): 5774- 5774. doi: 10.3390/molecules27185774
9	程富江, 刘廷志, 李祥祥, 等. 桉木APMP制浆废水抽出物提取及其抑藻效应研究[J]. 林产化学与工业, 2017, 37 (2): 57- 64.
	CHENG F J , LIU T Z , LI X X , et al. Extractives of organics from eucalyptus APMP effluents and its inhibition effect on growth of Microcystis aeruginosa[J]. Chemistry and Industry of Forest Products, 2017, 37 (2): 57- 64.
10	段希磊, 江修才, 栾耀祖. 活性污泥法对桉木APMP制浆废水处理效果研究[J]. 中华纸业, 2020, 41 (16): 23- 29.
	DUAN X L , JIANG X C , LUAN Y Z , et al. Effects of activated sludge on eucalyptus APMP wastewater treatment[J]. China Pulp & Paper Industry, 2020, 41 (16): 23- 29.
11	ABDOULAYEM G, 韦甜甜, 蒋仲琴, 等. 光催化-微生物直接耦合技术处理桉木化机浆废水的研究[J]. 造纸科学与技术, 2023, 42 (1): 47-54, 77.
	ABDOULAYE M G , WEI T T , JIANG Z Q , et al. Study on intimately coupling photocatalysis and biological technology for the treatment of eucalyptus chemical-mechanical pulp wastewater[J]. Paper Science and Technology, 2023, 42 (1): 47-54, 77.
12	LIU Q D, HOU J, WU J, et al. Intimately coupled photocatalysis and biodegradation for effective simultaneous removal of sulfamethoxazole and COD from synthetic domestic wastewater[J/OL]. Journal of Hazardous Materials, 2022, 423: 127063[2023-09-10]. https://doi.org/10.1016/j.jhazmat.2021.127063.
13	黄在恒, 秦香, 刘熹, 等. 桉木化机浆制浆废水多组分成分分析[J]. 中国造纸, 2022, 41 (6): 64- 70.
	HUANG Z H , QIN X , LIU X , et al. Multi-component analysis of eucalyptus chemi-mechanical pulping wastewater[J]. China Pulp & Paper, 2022, 41 (6): 64- 70.
14	BULAI I M , SPINA F , VARESE G C , et al. Wastewater bio-remediation using white rot Fungi: Validation of a dynamical system with real data obtained in laboratory[J]. Mathematical Methods in the Applied Sciences, 2018, 41 (11): 4192- 4207.
15	孙曼娜, 陈洪雷. APMP制浆废水高效降解菌的筛选及其降解动力学的研究[J]. 造纸科学与技术, 2014, 33 (3): 93- 96.
	SUN M N , CHEN H L . Isolation and degradation kinetics of a strain for degrading APMP effluent[J]. Paper Science & Technology, 2014, 33 (3): 93- 96.
16	何帅明, 莫立焕, 徐峻, 等. 活性炭负载铈催化臭氧处理桉木制浆废水[J]. 中国造纸, 2016, 35 (3): 1- 6.
	HE S M , MO L H , XU J , et al. Catalytic ozonation of eucalyptus pulping effluent by cerium loaded on activated carbon[J]. China Pulp & Paper, 2016, 35 (3): 1- 6.
17	TIAN Q W, FANG G G, DING L B, et al. ZnAl₂O₄/Bi₂MoO₆ hetero structures with enhanced photocatalytic activity for the treatment of organic pollutants and eucalyptus chemimechanical pulp wastewater[J/OL]. Materials Chemistry and Physics, 2020, 241: 122299[2023-09-10]. https://doi.org/10.1016/j.matchemphys.2019.122299.
18	JIANG Z Q, ABDOULAYE M G, WEI T T, et al. Treatment of eucalyptus chemical-mechanical pulp wastewater by coupling system of advanced catalytic oxidation and biodegradation: Synergistic effect of ozonation photocatalytic-microbial[J/OL]. Journal of Water Process Engineering, 2023, 55: 104071[2023-09-10]. https://doi.org/10.1016/j.jwpe.2023.104071.
19	HUANG Z H, QIN X, ZHU T, et al. Developing an efficient processing system treatment for the high concentration of eucalyptus chemical mechanical pulp wastewater[J/OL]. Molecules, 2022, 27(18): 5774[2023-09-10]. https://doi.org/10.3390/molecules27185774.
20	于芯宜, 徐家延, 陈方圆, 等. 5种植物精油抗菌性能研究及特征成分分析[J]. 保鲜与加工, 2022, 22 (10): 1- 9.
	YU X Y , XU J Y , CHEN F Y , et al. Investigation on antibacterial properties and characteristic componentsof five kinds of plant essential oils[J]. Storage and Process, 2022, 22 (10): 1- 9.
21	姜冬梅, 朱源, 余江南, 等. 芳樟醇药理作用及制剂研究进展[J]. 中国中药杂志, 2015, 40 (18): 3530- 3533.
	JIANG D M , ZHU Y , YU J N , et al. Research progress on pharmacological effects and preparations of linalool[J]. China Journal of Chinese Materia Medica, 2015, 40 (18): 3530- 3533.
22	郭俸钰, 陈文学, 陈海明, 等. 芳樟醇对大肠杆菌的抑菌作用机制[J]. 现代食品科技, 2020, 36 (4): 113- 118.
	GUO F Y , CHEN W X , CHEN H M , et al. Antibacterial mechanism of linalool against Escherichia coli[J]. Modern Food Science and Technology, 2020, 36 (4): 113- 118.
23	HATICE Z , BAYSAL A H . Antibacterial and antioxidant activity of essential oil terpenes against pathogenic and spoilage-forming bacteria and cell structure-activity relationships evaluated by SEM microscopy[J]. Molecules, 2014, 19 (11): 17773- 17798.

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桉木化学机械浆废水好氧生物抑制特性分析及降解规律研究

Analysis of Aerobic Biological Inhibition Characteristics and Degradation Law of Eucalyptus Chemical Mechanical Pulp Wastewater

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