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林产化学与工业 ›› 2014, Vol. 34 ›› Issue (3): 121-129.doi: 10.3969/j.issn.0253-2417.2014.03.021

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纤维素非均相ATRP接枝聚合的研究进展

庄志良, 祝黎, 吴伟兵, 戴红旗   

  1. 南京林业大学 江苏省制浆造纸科学与技术重点实验室, 江苏 南京 210037
  • 收稿日期:2013-08-12 出版日期:2014-06-25 发布日期:2014-06-25
  • 通讯作者: 戴红旗,教授,博士生导师,从事造纸清洁生产和纤维素材料研究;E-mail:daihq@vip.sina.com。 E-mail:daihq@vip.sina.com
  • 作者简介:庄志良(1989- ),男,江苏苏州人,硕士,主要从事纤维素接枝改性研究
  • 基金资助:
    国家自然科学基金资助项目(31200453,31270614);江苏省高校优势学科建设工程资助项目(无编号)

Progress on the Heterogeneous Cellulose Grafting Polymerization by ATRP

ZHUANG Zhi-liang, ZHU Li, WU Wei-bing, DAI Hong-qi   

  1. Jiangsu Provincial Key Lab of Pulp and Paper Science and Technology, Nanjing Forestry University, Nanjing 210037, China
  • Received:2013-08-12 Online:2014-06-25 Published:2014-06-25

摘要: 综述了近十年来ATRP法非均相接枝改性制备纤维素基功能材料的研究进展,重点描述了抗菌材料、超疏水材料、智能响应材料、生物相容性材料、吸附剂材料、增强复合材料等新型纤维素基功能材料的ATRP制备过程、新性能及在不同领域的应用,并分析了纤维素非均相ATRP接枝聚合中存在的问题及今后的发展前景。

关键词: 纤维素, ATRP, 接枝改性, 非均相, 功能材料

Abstract: This paper summarized the developments of cellulose-based functional materials produced by heterogeneous ATRP in the last ten years. The ATRP synthetic processes of various cellulose-based materials, e.g., cellulose surfaces with antibacterial, superhydrophobic or intelligent dual-responsive properties, materials possessing well biological compatibility,cellulose-based adsorbents and biocomposite reinforcements, were described. The functions and potential applications of these unique graft copolymers were introduced as well. Furthermore, this review also discussed the problems and forcasted the future of heterogeneous cellulose grafting polymerization by ATRP.

Key words: cellulose, ATRP, graft polymerization, heterogeneous, functional materials

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