欢迎访问《林产化学与工业》，
林产化学与工业

林产化学与工业 ›› 2013, Vol. 33 ›› Issue (6): 37-40.doi: 10.3969/j.issn.0253-2417.2013.06.007

• 1研究报告 • 上一篇    下一篇

以松香改性物为模板制备多孔二氧化硅的表征

马玉玲, 商旭婷, 崔淑芬, 韩世岩   

  1. 东北林业大学 生物质材料科学与技术教育部重点实验室, 黑龙江 哈尔滨 150040
  • 收稿日期:2012-11-29 修回日期:1900-01-01 出版日期:2013-12-30 发布日期:2013-12-30
  • 通讯作者: 韩世岩（1980-），女，内蒙古阿荣旗人，工程师，博士，主要从事松香衍生物基精细有机合成及功能性纳米材料的制备研究；E-mail：hanshiyan80@163.com。

Preparation of Porous Silica Using a Modified Rosin as Template

MA Yu-ling, SHANG Xu-ting, CUI Shu-fen, HAN Shi-yan   

  1. Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University，Harbin 150040，China
  • Received:2012-11-29 Revised:1900-01-01 Online:2013-12-30 Published:2013-12-30

PDF (PC)

392

摘要： 以正硅酸乙酯（TEOS）为起始原料，通过加入松香衍生物基双子表面活性剂为模板，采用溶胶-凝胶的方法制备了多孔二氧化硅材料；利用FT-IR、TEM、XRD对所制备的二氧化硅进行结构表征和形貌分析，以氮气吸附-脱附实验对其孔容孔径进行分析，结果表明：制备的二氧化硅粒径约为30 nm，颗粒之间有蠕虫状空隙，孔径主要集中在29.8 nm的介孔范围，比表面积和累积孔体积分别为116.83 m2/g、0.45 cm3/g。

关键词: 二氧化硅, 模板, 多孔

Abstract: Porous silica was prepared with tetraethyl orthosilicate as starting materials and rosin derivatives-based gemini surfactant as a template using sol-gel method. Its structure was characterized and the morphology was analysized by SEM,TEM and XRD. The pore volume and diameter was analysized by nitrogen adsorption-desorption experiments, too. The results showed that the particle size of silica was about 30 nm and worm-like voids were observed among the particles. The particle size mainly focuses on 29.8 nm in mesoporous range. The specific surface area and the cumulative pore volume are 116.83 m2/g and 0.45 cm3/g, respectively.

Key words: SiO2, template, porous

中图分类号: 

版权所有 © 中国林业科学研究院林产化学工业研究所　苏ICP备08107184号-3