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林产化学与工业 ›› 2009, Vol. 29 ›› Issue (1): 51-54.

• 研究报告 • 上一篇    下一篇

聚氯乙烯/聚乙烯蜡接枝马来酸酐/竹粉复合材料制备的研究

朱德钦, 生瑜, 刘希荣, 徐艳蓉   

  1. 福建师范大学化学与材料学院, 福建 福州 350007
  • 收稿日期:2007-09-19 修回日期:2008-06-16 出版日期:2009-02-28 发布日期:2009-02-28
  • 通讯作者: 生 瑜,研究员,硕士生导师,博士,从事高分子功能化改性、植物材料化学与利用;E-mail:shengyu@fjnu.edu.cn。

Study on Preparation of PVC/PEW-g-MAH/Bamboo Flour Composites

ZHU De-qin, SHENG Yu, LIU Xi-rong, XU Yan-rong   

  1. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
  • Received:2007-09-19 Revised:2008-06-16 Online:2009-02-28 Published:2009-02-28

摘要: 用自制的聚乙烯蜡接枝马来酸酐(PEW-g-MAH)改性竹粉填充聚氯乙烯(PVC),制备PVC/PEW-g-MAH/竹粉复合材料。通过正交设计法探讨PEW-g-MAH接枝率及用量、竹粉粒径及用量对复合材料力学性能的影响。结果表明,在100g PVC中,加入用0.3g 接枝率为1.16% 的PEW-g-MAH改性的0.425mm 竹粉30g,可得到力学性能较好的PVC/PEW-g-MAH/竹粉复合材料。其拉伸强度和缺口冲击强度分别由添加等量未改性竹粉体系的28.6MPa和3.05kJ/m2提高到30.01MPa和3.86kJ/m2

关键词: 正交设计, 聚乙烯蜡接枝马来酸酐, 竹粉, 聚氯乙烯, 力学性能

Abstract: Polyethylene wax grafted maleic anhydride (PEW-g-MAH) was applied to modify bamboo flour and the composites of poly(vinyl chloride) (PVC) filled with the modified bamboo flour were prepared. The effects of bamboo flour particle size and its dosage, grafting ratio of PEW-g-MAH and its dosage on the mechanical properties of PVC/PEW-g-MAH/bamboo flour composites were studied in detail by orthogonal-design experiments. Results show that the best condition for optimal mechanical property of PVC/PEW-g-MAH/bamboo flour composite is the following: grafting ratio of PEW-g-MAH 1.16% and its dosage 0.3g,particle size of bamboo flour 0.425mm and its dosage 30g. When modified bamboo flour was added, tensile strength and Charpy impact strength of the composite increased from respectively 28.6MPaand 3.05kJ/m2 of the composite filled with equal amount of unmodified bamboo flour to 30.01MPa and 3.86kJ/m2respectively.

Key words: orthogonal-design, polyethylene wax grafted maleic anhydride, bamboo flour, polyvinyl chloride, mechanical properties

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