脱氢枞酸基柔性单体的合成和聚合活性分析

doi:10.3969/j.issn.0253-2417.2014.02.007

Abstract

Abstract: (2-amethcryloyloxy)hexyl ester of dehydroabietic acid (DA-2-HHMA) with a yield of 41% was synthesized by the reaction of dehydroabietic chloride (DA-Cl) with hexanediol, and subsequently with methacryloyl chloride. The resulting product was then characterized by using FT-IR spectroscopy, ¹H NMR ¹³C NMR, DSC and GPC. The results showed that DA-2-HHMA could polymerize in the presence of initiator. The molecular weight of homompolymer is about 20 000-30 000 and its glass transition temperature is around -21.82 ℃.

Key words: dehydroabietic acid, (2-methacryloyloxy)hexyl ester of dehydroabietic acid, free radical polymerization

CLC Number:

TQ35

YU Juan, WANG Chun-peng, DING Li-na, CHEN Meng-yao, LIU Yu-peng, FU Li, CAI Zhi-hui, WANG Ji-fu, CHU Fu-xiang. Synthesis, Characterization and Polymerization Activity of Flexible Monomer Derived from Dehydroabietic Acid[J]. Chemistry and Industry of Forest Products, 2014, 34(2): 40-44.

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Synthesis, Characterization and Polymerization Activity of Flexible Monomer Derived from Dehydroabietic Acid

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