纳米镍催化α-蒎烯加氢合成顺式蒎烷的研究

Abstract

Abstract: Nanometer nickel was first used in hydrogenation of α-pinene: the conversion rate of raw material with nanometer nickel as catalyst was higher than that of Raney nickel and the selectivity of cis-pinane was higher than that with Pd/C. The suitable conditions of preparing cis-pinane by hydrogenation of α-pinene catalyzed by nanometer nickel were as follows: temperature 90℃, pressure 4.0 MPa, and dosage of catalyst 1.0% (based on the mass fraction of α-pinene).The conversion rate of α-pinene was 100%,and the selectivity of cis-pinane was 94.3%。

Key words: nanometer nickel, α-pinene, hydrogenation, cis-pinane

CLC Number:

TQ351.47

XIE Hui;YANG Sheng-jun;ZHANG Zhi-jie. STUDY ON HYDROGENATION OF α-PINENE TO CIS-PINANE CATALYZED BY NANOMETER NICKEL[J]. , 2005, 25(04): 56-58.

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STUDY ON HYDROGENATION OF α-PINENE TO CIS-PINANE CATALYZED BY NANOMETER NICKEL

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