歧化松香胺Schiff碱-铜配合物催化苯乙烯氧化反应的研究

›› 2007, Vol. 27 ›› Issue (S1): 99-104.

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Study on Oxidation of Styrene Catalyzed by Copper Complex of Disproportionated Rosin Amine Schiff Base

BAI Li-juan, LEI Fu-hou, MO Li-jun, LUO Ying, HUANG Yong-zhong

College of Chemistry and Ecological Engineering, Guangxi University For Nationalities, Nanning 530006, China

Received:2007-06-20 Revised:1900-01-01 Online:2007-10-20 Published:2007-10-20

Abstract

Abstract: The performance of cupric complex of disproportionated rosin amine Shiff base on catalyzing oxidation of styrene by H₂O₂ has been investigated. Factors affecting oxidation, such as solvents, temperature, reaction time, dosage of catalyst and the ratio of oxidant to alkene have been investigated. The optimum reaction conditions were: 5.000 g styrene with 15 mL 30% H₂O₂ at 80℃ for 6 h in the presence of 0.5% cupric complex in 1,4-dioxane. The conversion of styrene was 93.3%, the yield and selectivity of benzaldehyde were 66.8% and 71.7%, respectively.

Key words: disproportionated rosin amine, Schiff base, cupric complex, styrene, oxidation

CLC Number:

TQ351

BAI Li-juan;LEI Fu-hou;MO Li-jun;LUO Ying;HUANG Yong-zhong. Study on Oxidation of Styrene Catalyzed by Copper Complex of Disproportionated Rosin Amine Schiff Base[J]. , 2007, 27(S1): 99-104.

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Study on Oxidation of Styrene Catalyzed by Copper Complex of Disproportionated Rosin Amine Schiff Base

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