活性炭吸附硝基苯酚同分异构体的研究

doi:10.3969/j.issn.0253-2417.2014.02.020

Abstract

Abstract: Adsorption performance of activated carbon for nitro phenol isomers was investigated.The results showed that the highest adsorption capacity of o-nitrophenol,m-nitrophenol, p-nitrophenol on activated carbon are 676.03, 475.17 and 449.56 mg/g under the temperature of 25 ℃ and neutral conditions, respectively. The adsorption behavior of o-nitrophenol on activated carbon is different from the other two isomers. With the increasing of temperature, adsorption of o-nitrophenol in activated carbon was also increased. Under the acidic conditions, the adsorption amount of nitro phenol isomers was in the order of o-nitrophenol>p-nitrophenol>m-nitrophenol. Adsorption of m-nitrophenol can be improved in activated carbon by increasing the pH value. The adsorption isotherms of nitro phenol strictly accord with Langmuir equation, which is a single molecule layer absorption.

Key words: activated carbon, nitrophenol, isomer, adsorption

CLC Number:

LU Yong-yu, WANG Xiao-yan, ZHOU Jian-bin, PAN Rui, LIU Bin, MA Ye. The Adsorption Performance of Activated Carbon for Nitro Phenol Isomers[J]. Chemistry and Industry of Forest Products, 2014, 34(2): 113-118.

References

[1] 沈曾民, 张文辉, 张学军.活性炭材料的制备与应用[M].北京:化学工业出版社, 2006.
[2] BISCOE J, WARREN B E.An X-ray study of carbon black[J].Journal of Applied Physics, 1942, 13:364-371.
[3] 杨小红.活性炭生产及应用前景研究[J].池州师专学报, 2001, 15(3):138-140.
[4] KEITH L, TELLIARD W.Priority pollutants:I-A perspective view[J].Environmental Science & Technology, 1979, 13(4):416-423.
[5] 章思规, 章伟.精细化学品及中间体手册[M].北京:化学工业出版社, 2004.
[6] 刘范嘉, 张卫江, 谢英琴, 等.高效液相色谱法分离邻、对位硝基甲苯同分异构体[J].天津大学学报, 2006, 39(7):885-888.
[7] 于艳春, 李冠成, 刘德峥, 等.邻硝基苯酚中内氢键和内锂键构成的理论研究[J].内蒙古师大学报:自然科学汉文版, 1995(3):40-44.
[8] 谢红梅, 张丽, 许尊炼, 等.活性炭脱除废水中对硝基苯酚的研究[J].安徽农业科学, 2009, 35(19):9107-9109.
[9] 查飞, 常玥, 吕学谦, 等.坡缕石-活性炭-壳聚糖负载环糊精对硝基苯酚的吸附性质[J].精细化工, 2007, 24(3):209-212.
[10] 唐登勇, 郑正, 苏东辉, 等.活性炭纤维吸附废水中对硝基苯酚及其脱附研究[J].环境污染治理技术与设备, 2006, 7(1):98-101.
[11] LIAO Qiu, SUN Jing, GAO Lian.The adsorption of resorcinol from water using multi-walled carbon nanotubes[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2008, 312(2/3):160-165.
[12] 张霞, 聂英, 王毅, 等.改性煤基活性炭吸附对硝基苯酚的研究[J].石油化工应用, 2006, 25(5):14-16.
[13] 刘立柱, 孙明礼.对-硝基苯酚在碳纳米管上的吸附行为研究[J].中国科技信息, 2006(1):52.
[14] 朱利中, 杨坤.对硝基苯酚在沉积物上的吸附特性[J].环境化学, 2001, 20(5):449-454.
[15] 唐树和, 王京平, 许海燕.间硝基酚在复合功能树脂上的吸附热力学及动力学研究[J].化学世界, 2009, 50(6):321-323.
[16] 贾建国, 李闯, 朱春来, 等.活性炭的硝酸表面改性及其吸附性能[J].炭素技术, 2009, 28(6):11-15.
[17] 张会平, 叶李艺, 杨立春.物理活化法制备椰壳活性炭研究[J].厦门大学学报:自然科学版, 2004, 43(6):833-835.
[18] 近藤精一, 石川达雄, 安部郁夫.吸附科学[M].李国希, 译.北京:高等教育出版社, 2006:6-31.
[19] 赵振国.吸附作用应用原理[M].北京:化学工业出版社, 2005:326-354.
[20] 刘光启, 马连湘, 刘杰.化学化工物性数据手册:有机卷[M].北京:化学工业出版社, 2004:411.
[21] 李华昌, 符斌.实用化学手册[M].北京:化学工业出版社, 2006:354.

The Adsorption Performance of Activated Carbon for Nitro Phenol Isomers

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