桉木APMP制浆废液中主要有机组分的热解特性

doi:10.3969/j.issn.0253-2417.2014.04.014

林产化学与工业 ›› 2014, Vol. 34 ›› Issue (4): 83-89.doi: 10.3969/j.issn.0253-2417.2014.04.014

桉木APMP制浆废液中主要有机组分的热解特性

李霄虹, 武书彬, 赵玉双

华南理工大学制浆造纸工程国家重点实验室, 广东广州 510640

收稿日期:2013-05-13 出版日期:2014-08-25 发布日期:2015-08-18
作者简介:李霄虹（1988-），女，河北石家庄人，硕士生，主要从事生物质资源转化与利用方向的研究
基金资助:
国家973计划资助项目（2013CB228101）；国家自然科学基金资助项目（31270635，21176095）

Pyrolysis Characteristics of Main Organic Components in Eucalypt APMP Pulping Spent Liquor

LI Xiao-hong, WU Shu-bin, ZHAO Yu-shuang

State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Received:2013-05-13 Online:2014-08-25 Published:2015-08-18
Contact: 武书彬（1965-），男，教授，博士生导师，主要从事植物纤维类生物质化学结构、植物纤维类生物质转化为清洁能源和化工原料等方面的研究；E-mail：shubinwu@scut.edu.cn。 E-mail:shubinwu@scut.edu.cn

摘要/Abstract

摘要： 采用高温静态水平管式炉对桉木碱性过氧化氢机械浆（APMP）制浆废液固形物（ASLS）及其3种主要组分，即碱木质素（AL）、多糖（PLS）与木质素-碳水化合物复合体（LCC）在400~800℃ 进行快速热解，利用GC、GC/MS、FT-IR和SEM等手段，分析了各相热解产物组成与分布规律。结果表明，AL对ASLS热解液相产物得率影响较大，PLS对气相产物与固相产物得率的影响较大。ASLS热解产生H₂能力较强而与组分热解关系不大，高温阶段PLS热解生成CO能力显著提高，AL热解产生烃类化合物的能力明显高于其他组分。ASLS热解液相产物中的苯环化合物主要源自于AL热解产生，酚类与稠环化合物主要源自于AL和LCC组分热解产生，而酮类、呋喃类和酸类则是由AL、LCC和PLS热解后共同产生。ASLS、AL、PLS和LCC热解半焦表观形貌的差异比较明显。

关键词: 桉木, 碱木质素, 木质素-碳水化合物复合体, 多糖, 热解

Abstract: The eucalypt alkaline peroxide mechanical pulp (APMP) spent liquor solid (ASLS) and its three major organic components, i.e., alkali lignin(AL), polysaccharide(PLS) and lignin-carbohydrate complexes(LCC), were rapidly pyrolyzed at the temperature from 400℃ to 800℃ through a tubular furnace. The composition and distribution of the pyrolysis products were determined by gas chromatography (GC), gas chromatography coupled with mass spectrometry (GC/MS), Fourier transforms infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM), respectively. It was found that AL showed a significant effect on the yield of liquid products while PLS exhibited a remarkable influence on the yield of solid and gas products as ASLS was pyrolyzed. The yield of H₂ was as high as ASLS was pyrolyzed. It indicated no relation with the contents of AL, LCC and PLS. A large amount of CO was generated as PLS was pyrolyzed at high temperature. In contrast to ASLS, LCC and PLS, more hydrocarbon was generated as AL was pyrolyzed. Aromatics of ASLS pyrolysis liquid products were mainly from AL. And the pyrolysis of AL and LCC should be responsible for the generation of phenols and PAHs. Ketones, furans and acids were attributed to the pyrolysis of AL, LCC and PLS. The surface morphologies of ASLS, AL, LCC and PLS pyrolysis char were significantly different.

Key words: eucalypt, alkali lignin, lignin-carbohydrate complexes, polysaccharide, pyrolysis

中图分类号:

TQ35
TK6

李霄虹, 武书彬, 赵玉双. 桉木APMP制浆废液中主要有机组分的热解特性[J]. 林产化学与工业, 2014, 34(4): 83-89.

LI Xiao-hong, WU Shu-bin, ZHAO Yu-shuang. Pyrolysis Characteristics of Main Organic Components in Eucalypt APMP Pulping Spent Liquor[J]. Chemistry and Industry of Forest Products, 2014, 34(4): 83-89.

参考文献

[1] 劳嘉葆.造纸工业污染控制与环境保护[M].北京:中国轻工业出版社,2000:72-80.
[2] YAN Feng,LUO Si-yi,HU Zhi-quan,et al.Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor:Influence of temperature and steam on hydrogen yield and syngas composition[J].Bioresource Technology,2010,101(14):5633-5637.
[3] 刘江燕,武书彬,郭伊丽.制浆黑液固形物与工业木质素热解液化产物分析[J].林产化学与工业,2008,28(4):65-70.
[4] ZHANG Y,ASHIZAWA M,KAJITANIA S,et al.Proposal of a semi-empirical kinetic model to reconcile with gasification reactivity profiles of biomass chars [J].Fuel,2008,87(4/5):475-481.
[5] DEMIRBAS, A.Gaseous products from biomass by pyrolysis and gasification:Effects of catalyst on hydrogen yield[J].Energy Conversion and Management,2002,43(7):897-909.
[6] CHAUDHARI S T,BEJ S K,BAKHSHI N N,et al.Steam gasification of biomass-derived char for the production of carbon monoxide-rich synthesis gas[J].Energy & Fuels,2001,15(3):736-742.
[7] 张彩荣,叶道敏,崔永君,等.用废弃的半焦焦粉制活性炭工业性试验研究[J].煤炭转化,1999,22(2):75-78.
[8] 卢春兰,徐绍平,邓晓龙,等.生物质热解半焦炭的反应性研究[J].林产化学与工业,2005,25(3):16-20.
[9] DEMIRBAS, A.Pyrolysis and steam gasification processes of black liquor [J].Energy Conversion and Management,2002,43(7):877-884.
[10] FERDOUS D,DALAI A K,BEJ S K,et al.Pyrolysis of lignins:Experimental and kinetics studies [J].Energy Fuels,2002,16(6):1405-1412.
[11] BRODIN I,SJHOLM E,GELLERSTEDT G.The behavior of kraft lignin during thermal treatment [J].Journal of Analytical and Applied Pyrolysis,2010,87(1):70-77.
[12] GUO Da-liang,WU Shu-bin,LOU Rui,et al.Effect of organic bound Na groups on pyrolysis and CO₂-gasification of alkali lignin [J].Bioresources,2011,6(4):4145-4157.
[13] 戴涛,武书彬,郭大亮.硫酸盐法制浆黑液中主要有机组分的热解特性研究[J].燃料化学学报,2013,41(2):169-176.
[14] 赵玉双.化学机械浆制浆废液中主要有机组分热解特性的研究[D].广州:华南理工大学硕士学位论文,2013.
[15] 李天舒,刘荣厚.生物质快速热裂解主要参数对生物油产率的影响[J].环境污染治理技术与设备,2006,7(11):18-22.
[16] 戴涛.硫酸盐法制浆黑液中主要有机组分的热解特性研究[D].广州:华南理工大学硕士学位论文,2013.
[17] LV Gao-jin,WU Shu-bin,LOU Rui.Characteristics of corn stalk hemicellulose pyrolysis in a tubular reactor [J].Bioresources,2010,5(4):2051-2062.
[18] 彭云云,武书彬.麦草半纤维素的快速热裂解实验研究[J].燃料化学学报,2011,39(1):21-25.

桉木APMP制浆废液中主要有机组分的热解特性

Pyrolysis Characteristics of Main Organic Components in Eucalypt APMP Pulping Spent Liquor

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