生物质粗燃气重整净化技术及其研究进展

doi:10.3969/j.issn.0253-2417.2015.01.023

林产化学与工业 ›› 2015, Vol. 35 ›› Issue (1): 145-150.doi: 10.3969/j.issn.0253-2417.2015.01.023

• 综述评论 • 上一篇

生物质粗燃气重整净化技术及其研究进展

定明月¹, 熊伟^1,2, 涂军令^1,2, 张琦¹, 王铁军¹, 马隆龙¹, 李宇萍¹

1. 中国科学院广州能源研究所;可再生能源与天然气水合物重点实验室, 广东广州 510640;
2. 中国科学院研究生院, 北京 100049

收稿日期:2013-12-23 出版日期:2015-02-25 发布日期:2015-03-05
作者简介:定明月(1979-),男,湖北洪湖人,副研究员,硕士生导师,博士生,主要从事生物质能源研究工作
基金资助:
国家自然科学基金资助项目(51206172, U1362109);国家973计划资助(2013CB228105)

Progress in Reforming Purification Technology of Biomass Fuel Gas

DING Ming-yue¹, XIONG Wei^{1 2}, TU Jun-ling^{1 2}, ZHANG Qi¹, WANG Tie-jun¹, MA Long-long¹, LI Yu-ping¹

1. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-12-23 Online:2015-02-25 Published:2015-03-05
Contact: 王铁军(1972-),教授,博士生导师,主要从事生物质能源开发利用研究;E-mail:wangtj@ms.giec.ac.cn。 E-mail:wangtj@ms.giec.ac.cn

摘要/Abstract

摘要： 对生物质粗燃气中焦油净化和组分调变技术进行了综述,分析了影响气化炉内净化技术的气化工况条件和气化炉添加料等因素,介绍了天然矿物催化剂、碳酸盐催化剂、镍基催化剂等目前应用广泛的气化炉下游净化重整催化体系,简要介绍了粗生物燃气的组分调变,对该领域目前存在的问题和发展方向进行了讨论。

关键词: 生物质粗燃气, 焦油裂解, 组分调变, 天然矿物催化剂, 镍基催化剂

Abstract: The technologies on tar purification and component adjustment of biomass raw gases were reviewed. The influence factors such as gasification conditions and added materials of gasifier purification technology were analyzed. Some widely used gasifier downstream purification reforming catalysts such as natural mineral catalyst, carbonate catalyst and nickel-based catalyst were introduced. Component adjustment of biomass raw gases was presented briefly. The problems and development direction in this field were discussed,too.

Key words: biomass raw gas, tar cracking, syngas adjusting, natural mineral catalyst, nickel-based catalyst

中图分类号:

TQ35

定明月, 熊伟, 涂军令, 张琦, 王铁军, 马隆龙, 李宇萍. 生物质粗燃气重整净化技术及其研究进展[J]. 林产化学与工业, 2015, 35(1): 145-150.

DING Ming-yue, XIONG Wei, TU Jun-ling, ZHANG Qi, WANG Tie-jun, MA Long-long, LI Yu-ping. Progress in Reforming Purification Technology of Biomass Fuel Gas[J]. Chemistry and Industry of Forest Products, 2015, 35(1): 145-150.

参考文献

[1] 林伟刚,宋文立.丹麦生物质发电的现状和研究发展趋势[J].燃料化学学报,2005,33(6):650-655. LIN Wei-gang,SONG Wen-li.Power production from biomass in Denmark[J].Journal of Fuel Chemistry and Technology,2005,33(6):650-655.
[2] 汪俊锋,常杰,阴秀丽,等.生物质气催化合成甲醇的研究[J].燃料化学学报,2005,33(1):58-61. WANG Jun-feng,CHANG Jie,YIN Xiu-li,et al.Catalytic synthesis of methanol from biomass-derived syngas[J].Journal of Fuel Chemistry and Technology,2005,33(1):58-61.
[3] 赵先国,常杰,吕鹏梅,等.生物质流化床富氧气化的实验研究[J].燃料化学学报,2005,33(2):199-204. ZHAO Xian-guo,CHANG Jie,LV Peng-mei,et al.Biomass gasification under O₂-rich gas in a fluidized bed reactor[J].Journal of Fuel Chemistry and Technology,2005,33(2):199-204.
[4] CORELLA J,SANZ A.Modeling circulating fluidized bed biomass gasifiers:A pseudo-rigorous model for stationary state[J].Fuel Processing Technology,2005,86(9):1021-1053.
[5] KINOSHITA C M,WANG Y,ZHOU J.Tar formation under different biomass gasification conditions[J].Journal of Analytical and Applied Pyrolysis,1994,29(2):169-181.
[6] GIL J,CABALLERO M A,MARTÍN J A,et al.Biomass gasification with air in fluidized bed:Effect of in-bed use of dolomite under different operature conditions[J].Industrial and Engineering Chemistry Research,1999,38(11):4226-4235.
[7] NARVÁEZE I,ORÍO A,AZNAR M P,et al.Biomass gasification with air in an atmospheric bubbling fluidized bed,Effect of six operational variables on the quality of produced raw gas[J].Industrial and Engineering Chemistry Research,1996,35(7):2110-2120.
[8] YU Qi-zhuang,BRAGE C,CHEN Guan-xing,et al.Temperature impact on the formation of tar from biomass pyrolysis in a free-fall reactor[J].Journal of Analytical and Applied Pyrolysis,1997,40/41:481-489.
[9] BRAGE C,YU Qi-zhuang,CHEN Guan-xing,et al.Tar evolution profiles obtained from gasification of biomass and coal[J].Biomass and Bioenergy,2000,18(1):87-91.
[10] KNIGHT R A.Experience with raw gas analysis from pressurized gasification of biomass[J].Biomass and Bioenergy,2000,18(1):67-77.
[11] MOILAENE A,SAVIHARJU K.Gasification reactivities of biomass fuels in pressurized conditions and product gas mixtures[C] //BRIDGWATER A V,BOOCOCK D G B.Developments in thermochemical biomass conversion.London:Blackie,1997:828-837.
[12] HERGUIDO J,CORELLA J,GONZALEZ-SAIZ J.Steam gasification of lignocellulosic residues in a fluidized bed at a small pilot scale:Effect of the type of feedstock[J].Industrial and Engineering Chemistry Research,1992,31(5):1274-1282.
[13] AZNAR M P,CORRELA J,GIL J,et al.Biomass gasification with steam and oxygen mixtures at pilot scale and with catalytic gas upgrading Part Ⅰ:Performance of the gasifier[C] //BRIDGWATER A V,BOOCOCK D G B.Developments in thermochemical biomass conversion.London:Blackie,1997:1194-1208.
[14] MINKOVA V,MARINOV S P,ZANZI R,et al.Thermochemical treatment of biomass in a flow of steam or in a mixture of steam and carbon dioxide[J].Fuel Processing Technology,2000,62(1):45-52.
[15] WALAWENDER W P,HOVELAND D A,FAN L T.Steam gasification of alpha cellulose in a fluidized bed reactor[C] //OVEREND R P,MILNE T A,MUDGE L K.Fundamentals of thermochemical biomass conversion.London:Elsevier Applied Science,1985:897-910.
[16] CORELLA J,AZNAR M P,GIL J,et al.Biomass gasification in fluidized bed:Where to locate the dolomite to improve gasification[J].Energy and Fuels,1999,13(6):1122-1127.
[17] RAPAGNÁ S,JAND N,KIENNEMANN A,et al.Steam-gasification of biomass in a fluidized-bed of olivine particles[J].Biomass and Bioenergy,2000,19(3):187-197.
[18] BAKER E G,MUDGE L K,BROWN M D.Methanol and ammonia from biomass[J].Chemical Engineering Progress,1984,80(12):43-46.
[19] YOSHINORI T,YAMAGUCHI T,YAMASAKI K,et al.Catalyst for steam gasification of wood to ethanol synthesis gas[J].Industrial and Engineering Chemistry Process Design and Development,1984,23(2):225-229.
[20] AZNAR M P,CABALLERO M A,GIL J,et al.Commercial steam reforming catalysts to improve biomass gasification with steam-oxygen mixtures.2:Catalytic tar remove[J].Industrial and Engineering Chemistry Research,1998,37(1):2668-2680.
[21] DELGADO J,AZNAR M P,CORELLA J.Biomass gasification with steam in fluidized bed:Effectiveness of CaO,MgO and CaO-MgO for hot gas cleaning[J].Industrial and Engineering Chemistry Research,1997,36(5):1535-1543.
[22] HAUSERMAN W B.High-yield hydrogen production by catalytic gasification of coal or biomass[J].International Journal of Hydrogen Energy,1994,19(5):413-419.
[23] MUDGE L K,BAKER E G,MITCHELL D H,et al.Catalytic steam gasification of biomass for methanol and methane production[J].The Journal of Solar Energy Engineering,1985,107(1):88-92.
[24] ENCINAR J M,BELTRÁN F J,RAMIRO A,et al.Pyrolysis/gasification of agricultural residues by carbon dioxide in the presence of different additives:Influence of variables[J].Fuel Processing Technology,1998,55(3):219-233.
[25] BRIDGWATER A V,KUESTER J L.Research in Thermochemical Biomass Conversion[M].London:Elsevier Science Publishers,1988:157.
[26] ELLIOTT D C,BAKER E G,BUTNER R S,et al.Bench-scale reactor tests of low temperature,catalytic gasification of wet industrial wastes[J].Journal of Solar Energy Engineering,1993,115(1):52-56.
[27] YAMAGUCHI T,YAMASAKI K,YOSHIDA O,et al.Deactivation and regeneration of catalyst for steam gasification of wood to methanol synthesis gas[J].Industrial & Engineering Chemistry Research,1986,25(2):239-243.
[28] COURSON C,UDRON L,SWIERCZYHSKI D,et al.Hydrogen production from biomass gasification on nickel catalysts:Tests for dry reforming of methane[J].Catalysis Today,2002,76(1):75-86.
[29] RICHARDSON S M,GRAY M R.Enhancement of residue hydroprocessing catalysts by doping with alkali metals[J].Energy & Fuels,1997,11(6):1119-1126.
[30] BANGALA D N,ABATZOGLOU N,CHORNET E.Steam reforming of naphthalene on Ni-Cr/Al₂O₃ catalysts doped with MgO,TiO₂ and La₂O₃[J].AICHE Journal,1998,44(4):927-936.
[31] CHEN Yang-guang,TOMISHIGE K,YOKOYAMA K,et al.Catalytic performance and catalyst structure of nickel-magnesia catalysts for CO₂ reforming of methane[J].Journal of Catalysis,1999,184(2):479-490.
[32] BRADFORD M C J,VANNICE M A.Catalyst reforming of methane with carbon dioxide over nickel catalysts:Catalyst characterization and activity[J].Applied Catalysis A:General,1996,142(1):73-96.
[33] CHEN Ping,ZHANG Hong-bin,LIN Guo-dong,et al.Development of coking-resistant Ni-based catalyst for partial oxidation and CO₂-reforming of methane to syngas[J].Applied Catalysis A:General,1998,166(2):343-350.

生物质粗燃气重整净化技术及其研究进展

Progress in Reforming Purification Technology of Biomass Fuel Gas

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们