生物质碳基固体酸催化剂在纤维素水解中的研究进展

doi:10.3969/j.issn.0253-2417.2015.01.022

摘要/Abstract

摘要： 综述了生物质碳基固体酸催化剂催化纤维素水解的最新研究进展,首先介绍了催化剂制备的原料及方法,包括热解炭化-磺化法、硫酸炭化-磺化法、水热炭化-磺化法以及热解炭化-氧化-磺化法等,分析了催化纤维素水解的机理,简述了催化剂活性评价方法及促进水解反应的辅助方法,并展望生物质碳基固体酸催化剂在纤维素水解中的应用前景及发展方向。

关键词: 碳基固体酸, 催化剂, 纤维素, 水解

Abstract: In this paper,the latest research progress in cellulose hydrolysis by biomass carbon-based solid acid catalysts was reviewed. First raw materials and methods of catalyst preparation, including pyrolysis carbonization-sulfonated method, sulfuric acid charring-sulfonated, hydrothermal carbonization-sulfonated method and pyrolysis carbonization-oxidation-sulfonation method, were introduced. The mechanism of catalytic cellulose hydrolysis was analyzed, too. The factors and conditions affecting the catalytic hydrolysis reaction were discussed, and the applications and development direction of the carbonaceous solid catalysts in cellulose hydrolysis were prospected as well.

Key words: carbonaceous solid acid, catalyst, cellulose, hydrolysis

中图分类号:

TQ35

刘婉玉, 亓伟, 周劲松, 袁振宏, 庄新姝. 生物质碳基固体酸催化剂在纤维素水解中的研究进展[J]. 林产化学与工业, 2015, 35(1): 138-144.

LIU Wan-yu, QI Wei, ZHOU Jin-song, YUAN Zhen-hong, ZHUANG Xin-shu. Research Progress in Cellulose Hydrolysis by Carbonaceous Solid Acid[J]. Chemistry and Industry of Forest Products, 2015, 35(1): 138-144.

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