异长叶烷酮与水合肼的合成反应

doi:10.3969/j.issn.0253-2417.2016.02.019

林产化学与工业 ›› 2016, Vol. 36 ›› Issue (2): 129-133.doi: 10.3969/j.issn.0253-2417.2016.02.019

异长叶烷酮与水合肼的合成反应

王朋娜, 徐徐, 蔡涛, 黄建峰, 王石发

南京林业大学化学工程学院;江苏省生物质绿色燃料与化学品重点实验室, 江苏南京 210037

收稿日期:2015-03-02 出版日期:2016-04-25 发布日期:2016-04-26
通讯作者: 王石发,江西瑞金人,教授,博士生导师,研究领域为天然产物化学,有机合成化学;E-mail:wangshifa65@163.com。 E-mail:wangshifa65@163.com
作者简介:王朋娜(1987—),女,河北邢台人,硕士生,主要从事林产化学加工工程研究;E-mail:wangpengna0104@163.com
基金资助:
江苏省高校自然科学研究项目(14KJA220001);国家自然科学基金资助项目(31470592);江苏省生物质能源与材料重点实验室开放基金项目(JSBEM2014010)

Synthesis of Isolongifolane Ketone and Hydrazine

WANG Peng-na, XU Xu, CAI Tao, HUANG Jian-feng, WANG Shi-fa

College of Chemical Engineering, Nanjing Forestry University;Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing 210037, China

Received:2015-03-02 Online:2016-04-25 Published:2016-04-26

摘要/Abstract

摘要： 以异长叶烷酮为原料,与水合肼合成异长叶烷基席夫碱,采用单因试验和正交试验考察了不同条件对反应的影响。结果表明,以异长叶烷基席夫碱的得率为考察指标,其合成的最佳工艺条件为:以无水乙醇为反应溶剂,催化剂浓硫酸的用量0.6%(以总物料的体积为基准),反应温度78 ℃,反应时间24 h,n(异长叶烷酮):n(水合肼)为1:5,此条件下的得率为87.84%。采用GC-MS、FT-IR和 ¹H NMR 等手段对所得产物进行了分析与表征,证明合成了异长叶烷基席夫碱。

关键词: 异长叶烷酮, 水合肼, 席夫碱, 松节油

Abstract: Isolongifolane ketone Schiff base was synthesized with isolongifolane ketone and hydrazine as raw materials. The effects of different conditions on the reaction were studied by single factor and orthogonal experiments with the yield of the isolongifolane ketone Schiff base as the investigation index. The results showed that the optimized technological parameters were the catalyst dosage 0.6% (use the volume of all the material as the reference), ethanol as the solvent, reaction time 24 h, reaction temperature 78 ℃ and n(isolongifolane ketone):n(hydrazine) 1:5. Under these conditions, the yield of the product was 87.84%, and its chemical structure was analyzed by GC-MS,FT-IR and ¹H NMR spectra. They proved that the isolongifolane ketone Schiff base was synthesized.

Key words: isolongifolane ketone, hydrazine, Schiff base, turpentine

中图分类号:

TQ35

王朋娜, 徐徐, 蔡涛, 黄建峰, 王石发. 异长叶烷酮与水合肼的合成反应[J]. 林产化学与工业, 2016, 36(2): 129-133.

WANG Peng-na, XU Xu, CAI Tao, HUANG Jian-feng, WANG Shi-fa. Synthesis of Isolongifolane Ketone and Hydrazine[J]. Chemistry and Industry of Forest Products, 2016, 36(2): 129-133.

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异长叶烷酮与水合肼的合成反应

Synthesis of Isolongifolane Ketone and Hydrazine

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