醋酸纤维素的改性及应用研究进展

doi:10.3969/j.issn.0253-2417.2020.04.001

摘要/Abstract

摘要：

介绍了醋酸纤维素（CA）的亲水性、韧性、热塑性和生物降解性等性能特征，总结了3种不同醋酸纤维素的基本结构和市场应用情况，指出现阶段的CA还存在高温热稳定性差、机械强度低、膜易被污染等缺点。分析了物理改性和化学改性对CA性能的影响，指出聚合物的化学反应可以改变CA的结构或性质，使CA的耐污性、热塑性、选择性及重复利用性得到很大改善；而物理改性则可以提高CA膜的孔隙率和热稳定性，使膜的机械强度、金属离子排除率和水通量得到提高。对近年来CA在海水淡化、吸附烟气中有毒物质、制备生物医学膜、药物传递、组织修复再生、生物传感、户外防护及空气净化等方面的应用进行了概述，并对CA的市场前景和发展趋势进行了展望。

关键词: 醋酸纤维素, 改性, 应用

Abstract:

The hydrophilic, ductile, thermoplastic and biodegradable properties of cellulose acetate (CA) were introduced, and the basic structure and market application of three kinds of cellulose acetate were summarized.It was pointed out that CA still had some disadvantages such as poor thermal stability at high temperature, low mechanical strength and easily being contaminated. The impacts of the physical modification and chemical modification on the properties of CA were also reassessed.It could conclude that the chemical reaction with polymer could change the structure or properties of CA.The fouling resistance, thermoplastic, selective and reuse of the CA were improved greatly, while the physical modification could improve the porosity and thermal stability of CA membrane, and the membrane mechanical strength, metal ion exclusion rate and the water flux were improved. The applications of CA in seawater desalination, adsorption of toxic substances in flue gas, preparation of biomedical membrane, drug delivery, tissue repair and regeneration, biosensor, outdoor protection and air purification were also summarized, and the market prospect and development trend of CA were prospected.

Key words: cellulose acetate, modification, application

中图分类号:

TQ35

周慧敏,鲁杰,程意,吕艳娜,王海松. 醋酸纤维素的改性及应用研究进展[J]. 林产化学与工业, 2020, 40(4): 1-8.

Huimin ZHOU,Jie LU,Yi CHENG,Yanna LYU,Haisong WANG. Research Progress on Modification and Application of Cellulose Acetate[J]. Chemistry and Industry of Forest Products, 2020, 40(4): 1-8.

图/表 7

图1

图2

图3

图4

图5

图6

图7

参考文献 52

1	山炜巍, 周志宏. 醋酸纤维素的生产、应用与市场[J]. 乙醛醋酸化工, 2016, (4): 15- 21,31.
	SHAN W W , ZHOU Z H . Production, application and market of cellulose acetate[J]. Acetaldehyde Acetic Acid Chemical Industry, 2016, (4): 15- 21,31.
2	葛衡玮.离子液体下醋酸纤维素的合成反应研究[D].青岛:青岛科技大学, 2013.
	GE H W.The study on the synthesis of cellulose acetate in ionic liquid system[D]. Qingdao: Qingdao University of Science and Technology, 2013.
3	石纯, 李天诚, 杨静, 等. 竹醋酸纤维素膜的制备及其性能研究[J]. 林产化学与工业, 2018, 38 (5): 70- 76.
	SHI C , LI T C , YANG J , et al. Preparation and characterization of cellulose acetate films derived from bamboo[J]. Chemistry and Industry of Forest Products, 2018, 38 (5): 70- 76.
4	杨小佩.离子液体催化纤维素乙酰化制备醋酸纤维素的研究[D].上海:华东理工大学, 2015.
	YANG X P.Preparation of cellulose acetate by cellulose acetylation catalyzed by ionic liquid[D]. Shanghai: East China University of Science and Technology, 2015.
5	高立斌, 张素英, 史晟, 等. 醋酸纤维素的制备及其结构与性能[J]. 应用化工, 2020, 49 (1): 55- 59.
	GAO L B , ZHANG S Y , SHI S , et al. Synthesis, structure and properties of cellulose acetate[J]. Applied Chemical Industry, 2020, 49 (1): 55- 59.
6	马佳泰. 国产烟用二醋酸纤维素丝束规格发展概述[J]. 广东化工, 2020, 47 (3): 98- 107.
	MA J T . Overview of the development of domestic cellulose fiber specifications[J]. Guangdong Chemical Industry, 2020, 47 (3): 98- 107.
7	俞文骥, 杨齐, 邹耀邦, 等. 液晶显示用三醋酸纤维素的现状[J]. 塑料工业, 2017, 45 (4): 13- 16.
	YU W J , YANG Q , ZOU Y B , et al. Research status of cellulose triacetate in liquid crystal display[J]. China Plastics Industry, 2017, 45 (4): 13- 16.
8	SCHROETER J , FELIX F . Melting cellulose[J]. Cellulose, 2005, 12 (2): 159- 165.
9	JOLY N , GRANET R , BRANLAND P , et al. New methods for acylation of pure and sawdust-extracted cellulose by fatty acidderivatives-thermal and mechanical analyses of cellulose-based plastic films[J]. Journal of Applied Polymer Science, 2005, 97 (3): 1266- 1278.
10	王晋, 刘志华, 李春成, 等. 乙酸纤维素的应用及改性研究现状[J]. 化工进展, 2013, 32 (12): 2922- 2928.
	WANG J , LIU Z H , LI C C , et al. Progress of application and modification of cellulose acetate[J]. Chemical Industry and Engineering Progress, 2013, 32 (12): 2922- 2928.
11	童希源, 李甘. 纤维素的改性及在废水处理中的应用研究[J]. 广东蚕业, 2017, 51 (3): 25.
	TONG X Y , LIN G . Modification of cellulose and its application in wastewater treatment[J]. Guangdong Canye, 2017, 51 (3): 25.
12	原楠楠, 王鸿儒, 张焓. 醋酸纤维素改性水性聚氨酯的制备及性能[J]. 涂料工业, 2018, 48 (3): 43- 49.
	YUAN N N , WANG H R , ZHANG H . Preparation and properties of cellulose acetate modified waterborne polyurethane wood coatings[J]. Paint Coatings Industry, 2018, 48 (3): 43- 49.
13	AZARI S , ZOU L , CORNELISSEN E , et al. Facile fouling resistant surface modification of microfiltration cellulose acetate membranes by using amino acid L-DOPA[J]. Water Science Technology, 2013, 68 (4): 901- 908.
14	ABDEL-NABY A , AL-GHAMDI A . Chemical modification of cellulose acetate by N-(phenyl amino)maleimides:Characterization and properties[J]. International Journal of Biological Macromolecules, 2014, 68, 21- 27.
15	DEMIRCI S , CELEBIOGLU A , UYAR T . Surface modification of electrospun cellulose acetate nanofibers via RAFT polymerization for DNA adsorption[J]. Carbohydrate Polymers, 2014, 113, 200- 207.
16	ARSLAN O , AYTAC Z , UYAR T . Superhydrophobic, hybrid, electrospun cellulose acetate nanofibrous mats for oil/water separation by tailored surface modification[J]. ACS Applied Materials Interfaces, 2016, 8 (30): 19747- 19754.
17	TENORIO-ALFONSO A , SANCHEZ M , FRANCO J . Synthesis and mechanical properties of bio-sourced polyurethane adhesives obtained from castor oil and MDI-modified cellulose acetate:Influence of cellulose acetate modification[J]. International Journal of Adhesion and Adhesives, 2019, 95, 1- 11.
18	KENDOULI S , KHALFALLAH O , SOBTI N , et al. Modification of cellulose acetate nanofibers with PVP/Ag addition[J]. Materials Science in Semiconductor Processing, 2014, 28, 13- 19.
19	NOURI M , MARJANI A , TAJDARI M , et al. Preparation of cellulose acetate membrane coated by PVA/Fe₃O₄ nanocomposite thin film:An in situ procedure[J]. Colloid and Polymer Science, 2018, 296 (7): 1213- 1223.
20	SONG H M , ZHU L J , ZENG Z X , et al. High performance forward osmosis cellulose acetate(CA) membrane modified by polyvinyl alcohol and polydopamine[J]. Journal of Polymer Research, 2018, 25 (7): 159- 166.
21	NOURI M , MARJANI A . Surface modification of a cellulose acetate membrane using a nanocomposite suspension based on magnetic particles[J]. Cellulose, 2019, 26 (13/14): 7995- 8006.
22	CESAR N R , DE MENEZES A J , BOTARO V R . Nanocomposite of cellulose acetate reinforced with nanocrystals modified chemically:Modification with bifunctional reagent[J]. Polymer Composites, 2019, 40 (S1): E321- E322.
23	YANG S , WANG T , TANG R , et al. Enhanced permeability, mechanical and antibacterial properties of cellulose acetate ultrafiltration membranes incorporated with lignocellulose nanofibrils[J]. International Journal of Biological Macromolecules, 2020, 151, 159- 167.
24	王能, 丁恩勇. 高取代度高结晶度醋酸纤维素酯的制备与表征[J]. 林产化学与工业, 2005, 25 (1): 49- 52.
	WANG N , DING E Y . Preparation and characterization of cellulose acetate with high degree of substitution and high crystallinity[J]. Chemistry and Industry of Forest Products, 2005, 25 (1): 49- 52.
25	MORSY A , EBRAHIM S , KENAWY E , et al. Grafted cellulose acetate reverse osmosis membrane using 2-acrylamido-2-methylpro-panesulfonic acid for water desalination[J]. Water Science and Technology:Water Supply, 2016, 16 (4): 1046- 1056.
26	SHABAN M , ASHRRY E S , ABDELHAMID H , et al. Anti-biofouling of 2-acrylamido-2-methylpropane sulfonic acid grafted cellulose acetate membranes used for water desalination[J]. Chemical Engineering and Processing, 2020, 149, 107857- 107863.
27	VETRIVEL S , RANA D , SARASWATHI M S S A , et al. Cellulose acetate nanocomposite ultrafiltration membranes tailored with hydrous manganese dioxide nanoparticles for water treatment applications[J]. Polymers for Advanced Technologies, 2019, 30 (8): 1943- 1950.
28	TIAN Y , WU M , LIU R , et al. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment[J]. Carbohydrate Polymers, 2011, 83 (2): 743- 748.
29	ABURIDEH H , MERZOUK N , NACEUR M , et al. Thermal annealing effect on morphology and performance of polysulfone-cellulose acetate membranes:Application for water defluoridation[J]. Cellulose Chemistry and Technology, 2019, 53 (5/6): 583- 597.
30	RUSTEMEYER P . 5.2 CA filter tow for cigarette filters[J]. Macromolecular Symposia, 2004, 208 (1): 208- 292.
31	SUN P , YANG S , SUN X , et al. Functional porous carboxymethyl cellulose/cellulose acetate composite microspheres:Preparation, characterization, and application in the effective removal of HCN from cigarette smoke[J]. Polymers(Basel), 2019, 11 (1): 181- 191.
32	MOLAEIPOUR Y , GHAREHAGHAJI A , BAHRAMI H . Filtration performance of cigarette filter tip containing electrospu nanofibrous filter[J]. Journal of Industrial Textiles, 2014, 45 (2): 187- 198.
33	王晋, 刘志华, 张涛, 等. 肉桂酸改性醋酸纤维素的合成及其对烟气中氨的吸附[J]. 合成纤维工业, 2019, 42 (4): 36- 39.
	WANG J , LIU Z H , ZHANG T , et al. Synthesis of cellulose acetate modified with cinnamic acid and adsorption of ammonia in flue gas[J]. China Synthetic Fiber Industry, 2019, 42 (4): 36- 39.
34	肖凯丹, 张建波, 刘润昌, 等. 醋酸纤维素颗粒对主流烟气中焦油和苯酚释放量的影响[J]. 烟草科技, 2017, 50 (12): 70- 76.
	XIAO K D , ZHANG J B , LIU R C , et al. Influence of cellulose acetate particles on tar and phenol deliveries in mainstream cigarette smoke[J]. Tobacco Science and Technology, 2017, 50 (12): 70- 76.
35	DOND Y , LU X , WANG P , et al. "Click-chemical" modification of cellulose acetate nanofibers:A versatile platform for biofunctionalization[J]. Journal of Materials Chemistry B, 2018, 6 (28): 4579- 4582.
36	PENG L , LI H , MENG Y . Layer-by-layer structured polysaccharides-based multilayers on cellulose acetate membrane:Towards better hemocompatibility, antibacterial and antioxidant activities[J]. Applied Surface Science, 2017, 401, 25- 39.
37	IONITA M , CRICA L , VOICU S , et al. Synergistic effect of carbon nanotubes and graphene for high performance cellulose acetate membranes in biomedical applications[J]. Carbohydrate Polymers, 2018, 183, 50- 61.
38	KHOSHNEVISAN K , MALEKI H , SAMADIAN H , et al. Cellulose acetate electrospun nanofibers for drug delivery systems:Applications and recent advances[J]. Carbohydrate Polymers, 2018, 198, 131- 141.
39	VOICU S , CONDRUZ R , MITRAN V , et al. Sericin covalent immobilization onto cellulose acetate membrane for biomedical applications[J]. ACS Sustainable Chemistry Engineering, 2016, 4 (3): 1765- 1774.
40	NEACSU P , STARAS A , VOICU S , et al. Characterization and in vitro and in vivo assessment of a novel cellulose acetate-coated Mg-based alloy for orthopedic applications[J]. Materials(Basel), 2017, 10 (7): 686- 705.
41	LIU X , SHEN H , SONG S , et al. Accelerated biomineralization of graphene oxide-incorporated cellulose acetate nanofibrous scaffolds for mesenchymal stem cell osteogenesis[J]. Colloids and Surfaces B:Biointerfaces, 2017, 159, 251- 258.
42	HUANG H , DEAN D . 3-D printed porous cellulose acetate tissue scaffolds for additive manufacturing[J]. Additive Manufacturing, 2020, 31, 100927- 100950.
43	THAKUR N , SARGUR R A , SOPIHA K , et al. Thermoresponsive cellulose acetate-poly(N-isopropylacrylamide) core-shell fibers for controlled capture and release of moisture[J]. ACS Applied Materials Interfaces, 2017, 9 (34): 29224- 29233.
44	YADAV S , ILLA M P , RASTOGI T , et al. High absorbency cellulose acetate electrospun nanofibers for feminine hygiene application[J]. Applied Materials Today, 2016, 4, 62- 70.
45	SACARESCU L , SIMIONESCU M , SACARESCU G , et al. Transparent and fluorescent thin films of polysilane-SiQD nanocomposite:Cellulose acetate[J]. Cellulose, 2016, 23 (6): 3847- 3860.
46	ZHANG J , CAI Y , HOU X , et al. Fabrication and characterization of porous cellulose acetate films by breath figure incorporated with capric acid as form-stable phase change materials for storing/retrieving thermal energy[J]. Fibers and Polymers, 2017, 18 (2): 253- 263.
47	PAJNIK J , RADETIC M , STOJANOVIC D , et al. Functionalization of polypropylene, polyamide and cellulose acetate materials with pyrethrum extract as a natural repellent in supercritical carbon dioxide[J]. The Journal of Supercritical Fluids, 2018, 136, 70- 81.
48	ZHU M , CAO Q , LIU B , et al. A novel cellulose acetate/poly (ionic liquid) composite air filter[J]. Cellulose, 2020, 27, 3889- 3902.
49	OJSTRSEK A , FAKIN D , HRIBERNIK S , et al. Electrospun nanofibrous composites from cellulose acetate/ultra-high silica zeolites and their potential for VOC adsorption from air[J]. Carbohydrate Polymers, 2020, 236, 116071- 116091.
50	CHENG Y , ZHANG Q , FANG C , et al. Synthesis of N-doped porous carbon materials derived from waste cellulose acetate fiber via urea activation and its potential application in supercapacitors[J]. Journal of The Electrochemical Society, 2019, 166 (6): A1231- A1238.
51	CHEN W , ZHANG L , LIU C , et al. Electrospun flexible cellulose acetate-based separators for sodium-ion batteries with ultralong cycle stability and excellent wettability:The role of interface chemical groups[J]. ACS Applied Materials Interfaces, 2018, 10 (28): 23883- 23890.
52	JIA H , SUN N , DIRICAN M , et al. Electrospun kraft lignin/cellulose acetate-derived nanocarbon network as an anode for high-performance sodium-ion batteries[J]. ACS Applied Materials Interfaces, 2018, 10 (51): 44368- 44375.

[1]	王丽鑫, 徐雅雯, 李志森, 王鸿彪, 张乔会, 逄锦慧. 高强度醋酸纤维素/壳聚糖复合膜的制备及其性能研究[J]. 林产化学与工业, 2020, 40(4): 107-113.
[2]	白小杰,邓秀春,卓祖优,陈燕丹. 木棉纤维表面改性与高附加值利用研究进展[J]. 林产化学与工业, 2020, 40(2): 16-24.
[3]	许吉,翟兆兰,闫鑫焱,宋湛谦,商士斌,饶小平. 改性松香对速生杨木性能提升的研究[J]. 林产化学与工业, 2020, 40(2): 55-62.
[4]	李宁,陈智糠,张一甫. 酚化木质素改性酚醛树脂胶黏剂的制备及性能表征[J]. 林产化学与工业, 2019, 39(6): 95-101.
[5]	马红亮,陈健,焦健,邓拥军,孔振武,房桂干. 长链硅烷改性杨木纤维的制备及其表征[J]. 林产化学与工业, 2019, 39(3): 25-33.
[6]	徐士超,曾小静,董欢欢,赵振东. 萜类植物源除草活性物开发及应用研究进展[J]. 林产化学与工业, 2019, 39(2): 1-8.
[7]	赵存异,应文俊,史正军,杨海艳,郑志锋,杨静. 羟丙基化碱木质素的制备及其对纤维素酶水解的影响[J]. 林产化学与工业, 2019, 39(2): 109-114.
[8]	许利娜,杨小华,丁海阳,李梅,夏建陵. 氧化改性木质素磺酸钠-石墨烯复合量子点的制备及性能[J]. 林产化学与工业, 2019, 39(1): 29-34.
[9]	张昌伟,马余璐,陶冉,叶建中,王成章. 银杏叶聚戊烯醇的分离纯化及其亲水衍生物的合成[J]. 林产化学与工业, 2019, 39(1): 41-45.
[10]	高和,孙勇,唐兴,曾宪海,林鹿. 异氰酸酯改性竹材表面及其抗蚀性能研究[J]. 林产化学与工业, 2019, 39(1): 46-52.
[11]	马红亮, 陈健, 焦健, 邓拥军, 孔振武, 房桂干. 有机硅氧烷改性杨木纤维的制备及其表征[J]. 林产化学与工业, 2018, 38(6): 20-26.
[12]	许鹏博, 何晶, 俞娟, 范一民. 高锰酸钾改性汉麻秆芯对亚甲基蓝吸附性能的研究[J]. 林产化学与工业, 2018, 38(6): 81-87.
[13]	董阜豪, 陈莉晶, 郭佳雯, 徐徐, 王石发, 刘鹤. 生物质改性水性聚氨酯的合成及应用研究进展[J]. 林产化学与工业, 2018, 38(5): 1-8.
[14]	石纯, 李天诚, 杨静, 杨海艳, 邓佳, 史正军. 竹醋酸纤维素膜的制备及其性能研究[J]. 林产化学与工业, 2018, 38(5): 70-76.
[15]	陈启杰, 康美存, 郑学铭, 周丽玲, 王萍. 纳米纤维素在纸基功能材料中的应用进展[J]. 林产化学与工业, 2018, 38(4): 1-8.