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林产化学与工业

林产化学与工业 ›› 2014, Vol. 34 ›› Issue (1): 73-78.doi: 10.3969/j.issn.0253-2417.2014.01.012

• 研究报告 • 上一篇    下一篇

预处理对松木屑液化效率及产物化学组分的影响研究

贺小亮, 蒋剑春, 姜小祥, 杨中志   

  1. 中国林业科学研究院 林产化学工业研究所; 生物质化学利用国家工程实验室; 国家林业局 林产 化学工程重点开放性实验室; 江苏省 生物质能源与材料重点实验室, 江苏 南京 210042
  • 收稿日期:2013-01-23 出版日期:2014-02-25 发布日期:2014-03-05
  • 通讯作者: 蒋剑春（1955-），男，研究员，博士，博士生导师，主要从事生物质能源与炭材料的研究开发工作；E-mail：bio-energy@163.com。 E-mail:bio-energy@163.com
  • 作者简介:贺小亮（1989-），男，江西莲花人，硕士生，从事生物质液化方面的研究
  • 基金资助:
    林业公益性行业科研专项（201204801）

Effects of Pretreatment on Liquefaction of Pine Sawdust and Chemical Components of Product

HE Xiao-liang, JIANG Jian-chun, JIANG Xiao-xiang, YANG Zhong-zhi   

  1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab.for Biomass Chemical Utilization; Key and Open Lab.of Forest Chemical Engineering, SFA; Key Lab.of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
  • Received:2013-01-23 Online:2014-02-25 Published:2014-03-05

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摘要： 以松木屑为原料，甲醇-水混合溶剂为液化剂，考察了不同溶液预处理对木屑表面结构以及对液化转化率的影响，同时研究了反应温度、液化时间对木屑液化效果的影响。结果表明，不同预处理方法均改变了木屑结构，其中经氢氧化钠预处理过的木屑结构破坏最大，有利于增强液化反应活性；以氢氧化钠溶液预处理木屑时，反应温度为 320 ℃、液化时间为 10 min 时液化较合适，转化率达 92.4 %。GC-MS分析结果表明液化产物主要含有醇、醛、酮、酸、酯、酚类物质，不同的预处理对它们的含量有很大影响，未预处理过的木屑液化产物质量分数最多的是醛类物质，达到 40.588 %，氢氧化钠预处理和尿素预处理最多的分别是酮类和酸类物质，分别为30.878 %、25.311 %，而氢氧化钠与尿素共预处理木屑的液化产物中则酚类物质最多，为38.478 %。

关键词: 松木屑, 预处理, 液化

Abstract: Pine sawdust was liquefied using methanol-water mixed solvent as liquid agent. The effects of the pretreatment conditions on structural changes of the surface and the liquefaction conversion rate were investigated. The effects of reaction temperature and residence time on sawdust liquefaction were studied, too. The results indicated that different pretreatment can change the sawdust structure. The sawdust pretreated by NaOH had the most structural change. This could broaden the chemical reactivity. The conversion of sawdust was 92.4 % after pretreatment of sodium hydroxide solution at 320 ℃ for 10 min. GC-MS analysis showed that the liquid products mainly included alcohols, aldehydes, ketones, acids, esters and phenols. It was also found that pretreatment had an important effect on their contents which reached 40.588 %. The major component of liquid product produced with sawdust was aldehyde compounds and urea yields acid compounds. Their contents were 30.878 % and 25.311 %,respectively. The sawdust pretreated by NaOH trends to formate of ketone compounds,while sawdust pretreated by mixed NaOH and urea yields about 38.478 % phenolic compounds.

Key words: pine sawdust, pretreatment, liquefaction

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