在骨架镍上松香催化加氢反应的研究

Abstract

Abstract: Gas hold up and reaction effect of autoclave have been determined with different types of stirrers,which shows that the catalytic hydrogenation of rosin is a reaction of external diffusion control on Raney nickel for the purpose of eliminating the influence of external diffusion by using solvent and two layer stirrer with variation of agitation speed,which leads Raney nickel to show similar activity as that of the noble metal Pd/C catalyst.Relation between concentration of reactants and products and reaction time has been traced on line in the course of reaction.Result shows that hydrogenations of abietic acid to abietenoic acid and abietanoic acid are parallel reactions under the reaction condition of 17℃,5.0MPa.

Key words: Raney nickel, rosin, catalytic hydrogenation

CLC Number:

TQ351.471

CHEN Xiao-peng;WANG Lin-lin;MA Jian;YANG Cheng-li . STUDY ON CATALYTIC HYDROGENATION OF ROSIN ON RANEY NICKEL[J]. , 2002, 22(1): 12-16.

[1]	XU Jiali, ZHANG Haibo, YAO Shufeng, GAO Hong, SHANG Shibin. Research Progress of Forestry Biomass-based Film Preservatives of Fruit and Vegetable [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 10-16.
[2]	SHEN Chen, WANG Yaming, JIANG Lihong, ZHENG Yan'e, SONG Shuangshuang, LAI Qian. Preparation and Characterization of Ni-P/rGO Composite Catalysts and Their Hydrogenation Properties of Rosin [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 57-64.
[3]	CHENG Zenghui, ZHANG Daihui, WANG Jifu, WANG Chunpeng, CHU Fuxiang, XU Feng. Preparation of Monodisperse Rosin-based Polymer Microspheres by Dispersion Polymerization [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 39-45.
[4]	LUO Yunlong, SHEN Minggui, CAI Zhaosheng, SHANG Shibin, SONG Zhanqian. Synthesis and Antiviral Activity Evaluation of Dehydroabietic Acid Amide Derived 3,4-Dihydropyrimidinthiones [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 46-52.
[5]	LI Xiaohao, XIE Congxia. Preparation, Characterization and Performance for RosinHydrogenation of Pd/mpg-C₃N₄ Catalyst [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 73-80.
[6]	FENG Xiaolong, LI Xiaotong, HUANG Lingge, GUO Kai. Preparation and Properties of Ultraviolet-curing Modified Rosin Methacrylate [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 45-52.
[7]	YUE Xiantian, ZENG Tao, LING Qinghua, WANG Xueyuan. Isomerization of Resin Acid Under Desorption-distillation Processes with Different Medium [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 124-128.
[8]	LI Zhaoshuang, LI Jianfang, LIU He, SHANG Shibin, SONG Zhanqian. Research Progress of Biological Activity of Rosin Derivatives [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 17-24.
[9]	ZHANG Haibo, JIANG Jianxin, GAO Hong, SHANG Shibin, SONG Zhanqian. Drug Release and Kinetics Properties of Rosin-based Polyacrylamide Hydrogels [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 25-32.
[10]	LIN Haixia, YANG Mingsheng, TIAN Chao, HAN Chunrui. Self-assembly,Mixed System and Drug-loading Research of Rosin-based Tertiary Amine Salt [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 59-66.
[11]	LI Qiaoguang, LIU He, LI Jianfang, SHANG Shibin, SONG Zhanqian. Synthesis of Rosin Based Crosslinking Agent and Its Effect on Properties of Cured Silicone Rubber [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 87-93.
[12]	LI Qiaoguang, LIU He, SHANG Shibin, SONG Zhanqian. Research Progress of Rosin and Its Derivatives in Polymer Synthesis [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 23-29.
[13]	WU Jia, LU Youda, YANG Hui, LAI Xichen, LIN Rihui, CHEN Qiyong. Absorption of Benzopyrene by Rosin Starch Ester [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 67-72.
[14]	CHEN Hong-xia, WANG Cheng-zhang, ZHOU Hao, TAO Ran, YE Jian-zhong, LI Wen-jun. Separation and Identification of Phenolic Compounds of Ethanol Extract from Lacquertree Woods [J]. Chemistry and Industry of Forest Products, 2016, 36(6): 1-8.
[15]	WANG Hong-qin, WANG Ya-ming, JIANG Li-hong, JIN Yan-qiong. Preparation and Catalytic Activity of[Rh(COD)Cl]₂ Catalyst for Turpentine Hydrogenation [J]. Chemistry and Industry of Forest Products, 2016, 36(6): 56-62.

STUDY ON CATALYTIC HYDROGENATION OF ROSIN ON RANEY NICKEL

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments