炭基固体酸H-Al/AC的制备、表征及其催化葡萄糖制5-HMF

doi:10.3969/j.issn.0253-2417.2021.04.009

Abstract

Abstract:

A carbon-based solid acid catalyst(H-Al/AC) containing Brønsted(B) acid and Lewis(L) acid was prepared by H₂SO₄ sulfonation and AlCl₃ immersion using coconut shell activated carbon(AC) as carrier. This catalyst was used to prepare 5-hydroxymethylfurfural(5-HMF) from glucose in a biphasic system(water/2-sec-butylphenol) by hydrothermal rection. The catalyst was characterized by SEM, BET, XRD, NH₃-TPD and pyridine infrared to investigate the influence of preparation conditions on the structure and activity of the catalyst. The results showed that the catalyst activity reached the highest after being sulfonated with 98% H₂SO₄ and immersed in saturated AlCl₃ solution for 4 h. The catalyst showed an amorphous carbon structure with the specific surface area of 1 139.31 m²/g, B acid amount 4.213 μmol/g and L acid amount 29.97 μmol/g, respectively. The catalytic performance of the prepared catalyst was investigated for the conversion of glucose to 5-HMF in biphasic system when the ratio of aqueous phase to organic phase was 1:2, and the results showed that the highest 5-HMF yield of 25.14% were obtained at 180℃ for 210 min with 0.025 g of catalyst. The reaction path of glucose conversion to 5-HMF was as follows: glucose was isomerized into fructose under the action of Lewis acid in the aqueous phase. Fructose was dehydrated under the catalysis of Brønsted acid to generate 5-HMF. 5-HMF was extracted into 2-sec-butylphenol(SBP), and the generated water was retained in the aqueous phase. The catalyst cycle stability test showed that the activity of the catalyst was 86% of the initial activity after repeated use for five times.

Key words: carbon-based solid acid, glucose, 5-hydroxymethyl furfural, biphasic system, hydrothermal

CLC Number:

TQ35

Yadong DU, Chunhui MA, Yu YIN, Wei LI, Sha LUO, Shouxin LIU. Catalytic Performance of Carbon-based Solid Acid H-Al/AC in Glucose to 5-Hydroxymethylfurfural Reaction[J]. Chemistry and Industry of Forest Products, 2021, 41(4): 62-68.

Figures/Tables 9

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References 17

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样品 sample	S_BET/ (m²·g^-1)	V_tot/ (cm³·g^-1)	V_mic/ (cm³·g^-1)	S_mic/ (m²·g^-1)	平均孔径/nm average pore size	酸量acid density(200 ℃)/(μmol·g^-1)
样品 sample	S_BET/ (m²·g^-1)	V_tot/ (cm³·g^-1)	V_mic/ (cm³·g^-1)	S_mic/ (m²·g^-1)	平均孔径/nm average pore size	B	L	B+L
AC	1362.40	0.68	0.56	1212.80	2.01	1.047	13.38	14.43
H-Al/AC	1139.31	0.62	0.41	824.79	2.19	4.213	29.97	34.18

水相/mL water phase	有机相(SBP)/mL organic phase	催化剂添加量/g catalyst addition	5-HMF产率/% 5-HMF yield	葡萄糖转化率/% glucose conversion rate
60	0	0.020	17.11	65.91
50	10	0.020	19.25	67.34
40	20	0.020	20.92	68.56
30	30	0.020	21.11	71.25
20	40	0.020	24.57	72.54
10	50	0.020	15.52	71.02
0	60	0.020	5.12	46.31
20	40	0	3.50	55.31
20	40	0.010	9.71	63.20
20	40	0.020	18.85	69.12
20	40	0.025	22.47	72.50
20	40	0.050	17.75	72.61
20	40	0.075	15.18	73.00
20	40	0.100	9.20	72.80

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Catalytic Performance of Carbon-based Solid Acid H-Al/AC in Glucose to 5-Hydroxymethylfurfural Reaction

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