欢迎访问《林产化学与工业》，
林产化学与工业

林产化学与工业 ›› 2013, Vol. 33 ›› Issue (2): 31-36.doi: 10.3969/j.issn.0253-2417.2013.02.005

• 研究报告 • 上一篇    下一篇

丁腈橡胶粉改性酚醛树脂泡沫的性能与微观结构研究

李玲1, 许玉芝1, 王春鹏1, 储富祥1,2   

  1. 1. 中国林业科学研究院 林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省 生物质能源与材料重点实验室, 江苏 南京 210042;2. 中国林业科学研究院 林业新技术研究所, 北京 1000091
  • 收稿日期:2012-12-10 修回日期:1900-01-01 出版日期:2013-04-30 发布日期:2013-04-30
  • 通讯作者: 许玉芝(1974-),女,副研究员,博士,主要从事生物质胶黏剂基材料的研究;E-mail:bxxqzgl@163.com。

Properties and Microstructure of Phenolic Foam Modified by Nitrile Butadiene Rubber Powder

LI Ling1, XU Yu-zhi1, WANG Chun-peng1, CHU Fu-xiang1,2   

  1. 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry, CAF, Beijing 100091, China
  • Received:2012-12-10 Revised:1900-01-01 Online:2013-04-30 Published:2013-04-30

PDF (PC)

1131

摘要： 应用丁腈橡胶粉(NBRP)对酚醛树脂进行改性,再与其他助剂复合在70 ℃制备改性酚醛泡沫材料。分析了NBRP的改性方式对酚醛泡沫材料性能的影响,进一步讨论了NBRP前期改性加入量对酚醛泡沫机械性能、易碎性能、燃烧性能和泡孔微观结构的影响。研究表明:NBRP前期改性酚醛泡沫性能优异,其中添加量2%时综合性能最佳,这为丁腈橡胶粉改性酚醛树脂提供了科学依据。

关键词: 酚醛泡沫, 丁腈橡胶胶粉, 改性, 机械性能

Abstract: The performance of phenolic-formaldehyde(PF) foam was improved by co-foaming of PF resin with nitrile butadiene rubber power(NBRP) and other additives in the closing mould at 70 ℃. The influence of NBRP modification method including pre-NBRP and post-NBRP on the properties of phenolic foams was studied. The effects of amount of pre-NBRP modification on mechanical properties, fragile properties, flame-retardant properties and microscopic structure of NBRP-PF foam were further investigated. The results indicated that the pre-NBRP-modified PF foam had better properties compared with that of Post-NBRP, when 2 % NBRP was used. The overall performance of PF foam was the best. This could be a consequence of cooperation of NBRP and PF resin.

Key words: phenolic foam, nitrile butadiene rubber power, modification, mechanical property

中图分类号: 

版权所有 © 中国林业科学研究院林产化学工业研究所　苏ICP备08107184号-3