地沟油热裂解制备燃料油的研究

doi:10.3969/j.issn.0253-2417.2016.03.010

林产化学与工业 ›› 2016, Vol. 36 ›› Issue (3): 67-72.doi: 10.3969/j.issn.0253-2417.2016.03.010

地沟油热裂解制备燃料油的研究

赵佳平¹, 蒋剑春^1,2, 徐俊明^1,2, 杨华¹

1. 中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏南京 210042;
2. 中国林业科学研究院林业新技术研究所, 北京 100091

收稿日期:2015-06-08 出版日期:2016-06-25 发布日期:2016-07-07
通讯作者: 蒋剑春,男,研究员,博士,博士生导师,主要从事生物质能源与活性炭方面的研究;E-mail:bio-energy@163.com。 E-mail:bio-energy@163.com
作者简介:赵佳平(1989-),女,江苏常州人,硕士生,主要从事油脂方面的研究
基金资助:
国家自然科学基金资助项目(31422013)

Biodiesel Production from Pyrolysis of Waste Cooking Oils

ZHAO Jia-ping¹, JIANG Jian-chun^1,2, XU Jun-ming^1,2, YANG Hua¹

1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China

Received:2015-06-08 Online:2016-06-25 Published:2016-07-07

摘要/Abstract

摘要： 为了实现地沟油的有效回收利用,采用热裂解和催化酯化工艺制备了地沟油生物燃料油,并把制得的燃料油与0^#柴油调合进行台架试验测试。结果表明:通过热裂解反应,油品的物质组成发生了变化,热裂解油主要组分为C10~C18的烷烃、烯烃和羧酸等,其中烃类质量分数占64%。裂解油再经过催化酯化反应,油品的燃料性能进一步提高,所制得的生物燃料油性能如下:酸值0.29 mg/g,黏度2.58 mm²/s,热值为44 MJ/kg,冷凝点-7℃,冷滤点-3℃,各性能都符合国家生物柴油标准。台架试验测试混合燃料的动力性能和排放性能,数据表明地沟油生物燃料油对于柴油机动力性能影响甚微,排放尾气环保性能更优。

关键词: 地沟油, 热裂解, 酯化, 生物燃料油

Abstract: Waste cooking oil were used to produce biodiesel by pyrolysis and esterification reaction The results showed that main components in pyrolytic oil was main alkanes and alkenes with the carbon chain between C10 and C18(total content reach 64%), and a small amount of carboxylic acid compounds. Fuel properties of pyrolytic products were great promoted by esterification reaction. The esterificatied product exhibited good performances with acid value 0.29 mg/g, viscosity 2.58 mm²/s, calorific value 44 MJ/kg, pour point -7℃, and cold filter plugging point -3℃. They met national standard biodiesel. The performance of diesel engine when blend 0^# diesel oil with waste cooking oil biodiesel was tested. The test showed that power and torque of the blending fuel are basically the same, and exhaust emissions of diesel engine are more green than 0^# diesel.

Key words: waste cooking oil, pyrolysis, esterification, biodiesel

中图分类号:

TQ645.6

赵佳平, 蒋剑春, 徐俊明, 杨华. 地沟油热裂解制备燃料油的研究[J]. 林产化学与工业, 2016, 36(3): 67-72.

ZHAO Jia-ping, JIANG Jian-chun, XU Jun-ming, YANG Hua. Biodiesel Production from Pyrolysis of Waste Cooking Oils[J]. Chemistry and Industry of Forest Products, 2016, 36(3): 67-72.

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地沟油热裂解制备燃料油的研究

Biodiesel Production from Pyrolysis of Waste Cooking Oils

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