一种松香基阴离子表面活性剂的合成与性能研究

doi:10.3969/j.issn.0253-2417.2022.01.007

林产化学与工业 ›› 2022, Vol. 42 ›› Issue (1): 51-56.doi: 10.3969/j.issn.0253-2417.2022.01.007

一种松香基阴离子表面活性剂的合成与性能研究

庞淑敬, 陈豪, 宋冰蕾()

江南大学化学与材料工程学院, 合成与生物胶体教育部重点实验室, 江苏无锡 214122

收稿日期:2020-11-16 出版日期:2022-02-28 发布日期:2022-03-11
通讯作者: 宋冰蕾 E-mail:ccfsbl@126.com
作者简介:宋冰蕾, 副教授, 博士, 硕士生导师, 主要从事表面活性剂的合成、性能与应用研究; E-mail: ccfsbl@126.com
庞淑敬(1995-), 女, 安徽宿州人, 硕士生, 从事松香基化合物的研究
基金资助:
国家自然科学基金资助项目(31670575)

Synthesis and Properties of a Rosin-based Anionic Surfactant

Shujing PANG, Hao CHEN, Binglei SONG()

The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China

Received:2020-11-16 Online:2022-02-28 Published:2022-03-11
Contact: Binglei SONG E-mail:ccfsbl@126.com

摘要/Abstract

摘要：

以脱氢枞酸(DA)和6-氨基己酸为原料，经酰氯化、酰胺化和皂化等反应合成了一种松香基阴离子表面活性剂6-脱氢枞酰胺基己酸钠(R-6)。首先利用二维核磁技术对脱氢枞酸的氢谱和碳谱信号进行了全面解析，并用¹H NMR和FT-IR确证了终产品的结构，进一步考查了R-6的溶解性能、表面张力和泡沫性能。研究结果表明：在室温下，R-6在水中溶解性极好，溶解度在800 mmol/L以上；R-6的临界胶束浓度(C_cmc)为5.89 mmol/L，对应的表面张力(γ_cmc)为40.46 mN/m。随着表面活性剂浓度的增加，稳泡能力越来越强，浓度为10 mmol/L时，泡沫半衰期高达1 966 min。

关键词: 脱氢枞酸, 氨基酸, 表面活性剂, 泡沫, 溶解性

Abstract:

Using dehydroabietic acid (DA) and 6-aminocaproic acid as the raw materials, a rosin-based amino acid surfactant (R-6) was synthesized via reactions of chlorination, amidation and saponification reactions.The ¹H NMR and ¹³C NMR signals of dehydroabietic acid were analyzed by using 2D NMR techniques, and the structure of the final product was also confirmed by ¹H NMR and FT-IR.The solubility, surface tension and foam properties of R-6 were investigated.The results showed that at room temperature, R-6 showed excellent solubility of above 800 mmol/L in water.The critical micelle concentration (C_cmc) of the surfactant was 5.89 mmol/L, and the surface tension (γ_cmc) corresponding to C_cmc was 40.46 mN/m.With the increase of surfactant concentration, R-6 exhibited strong ability in stabilizing foams.When the concentration of R-6solution was 10 mmol/L, the foam half-life was as high as 1 966 min.

Key words: dehydroabietic acid, amino acid, surfactant, foam, solubility

中图分类号:

TQ35

庞淑敬, 陈豪, 宋冰蕾. 一种松香基阴离子表面活性剂的合成与性能研究[J]. 林产化学与工业, 2022, 42(1): 51-56.

Shujing PANG, Hao CHEN, Binglei SONG. Synthesis and Properties of a Rosin-based Anionic Surfactant[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 51-56.

图/表 8

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一种松香基阴离子表面活性剂的合成与性能研究

Synthesis and Properties of a Rosin-based Anionic Surfactant

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