竹热解气化副产物改性制备高性能成型活性炭及其表征

doi:10.3969/j.issn.0253-2417.2023.04.001

林产化学与工业 ›› 2023, Vol. 43 ›› Issue (4): 1-8.doi: 10.3969/j.issn.0253-2417.2023.04.001

竹热解气化副产物改性制备高性能成型活性炭及其表征

徐茹婷¹, 马名哲¹, 应浩¹, 孙昊¹^,*(), 金彦任², 赵婷²

1. 中国林业科学研究院林产化学工业研究所；江苏省生物质能源与材料重点实验室；国家林业和草原局林产化学工程重点实验室；林木生物质低碳高效利用国家工程研究中心；江苏省林业资源高效加工利用协同创新中心，江苏南京 210042
2. 山西新华防化装备研究院有限公司，山西太原 030008

收稿日期:2022-04-07 出版日期:2023-08-28 发布日期:2023-08-26
通讯作者: 孙昊 E-mail:15850534739@163.com
作者简介:孙昊，副研究员，博士，主要从事生物质基炭材料基础与应用研究；E-mail：15850534739@163.com
徐茹婷(1994—)，女，安徽宣城人，助理研究员，硕士，主要从事炭质吸附材料的制备与应用研究
基金资助:
浙江省省院合作林业科技项目(2020SY03)

Preparation and Characterization of High Performance Formed Activated Carbon by Modification of By-products from Bamboo Gasification

Ruting XU¹, Mingzhe MA¹, Hao YING¹, Hao SUN¹^,*(), Yanren JIN², Ting ZHAO²

1. Institute of Chemical Industry of Forest Products, CAF; Key Lab. of Biomass Energy and Material, Jiangsu Province; Key Lab. of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass; Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing 210042, China
2. Shanxi Xinhua Chemical Defense Equipment Research Institute CO., LTD., Taiyuan 030008, China

Received:2022-04-07 Online:2023-08-28 Published:2023-08-26
Contact: Hao SUN E-mail:15850534739@163.com

摘要/Abstract

摘要：

以竹热解气化产生的炭副产物为原料，高分子化改性焦油等为黏结剂，经液压成型、热解交联、水蒸气活化制备竹质成型活性炭，分析了不同黏结剂的成型机制，考察了黏结剂类型、改性焦油添加量、活化温度、活化时间对活性炭性能的影响，结果发现：焦油经芳香化交联改性后，相对分子质量和热稳定性提高了，对竹炭孔道的堵塞作用减轻了，炭颗粒间的黏结和热解交联作用增强了，可制备高性能的竹质成型活性炭；以40 g竹炭粉为原料，在改性焦油添加量12 g、炭化温度550 ℃、炭化时间90 min、水蒸气活化温度850 ℃、水蒸气活化时间80 min的条件下制得成型活性炭，其碘吸附值1 232 mg/g，亚甲基蓝(MB)吸附值240 mg/g，强度91%，得率48.5%，比表面积和总孔容分别为1 157 m²/g和0.478 1 cm³/g，对甲苯和四氯化碳的吸附率分别为385 mg/g和75.2%，且成型活性炭的微孔孔容与甲苯和四氯化碳吸附率呈正比关系。

关键词: 成型活性炭, 改性焦油, 黏结剂, 微孔容积, 气相吸附

Abstract:

Using carbon by-products produced by bamboo gasification as raw material and the polymerized modified tar as the binder, the bamboo formed activated carbon was obtained by hydro-forming, pyrolytic cross-linking and followed by water vapor activation. The forming mechanism of different binders were analyzed, and the properties of activated carbon were investigated, such as the variety of the binder, the adding amount of modified tar, the activation temperature and the activation time. The results showed that after modification by aromatization and cross-linking, the molecular weight and thermal stability of tar were improved; the blocking effect of bamboo char pore channels was reduced; the bonding and pyrolytic cross-linking between char particles were enhanced; and high-performance bamboo forming activated carbon could be prepared. Using 40g bamboo charcoal as raw material, the tar addition amount of 12 g, the carbonization temperature of 550 ℃, the carbonization time of 90 min, the activation temperature of 850 ℃ and the activation time of 80 min, the iodine adsorption value of the formed carbon was 1 232 mg/g, the methylene blue(MB) adsorption value was 240 mg/g, the strength was 91%, and the yield was 48.5%. The specific surface area and total pore volume were 1 157 m²/g and 0.478 1 cm³, respectively. The adsorption rates of toluene and carbon tetrechloride were 385 mg/g and 75.2%, respectively. And the adsorption rate of toluene and carbon tetrechloride was positively related to the micropore volume of formed activated carbon.

Key words: formed activated carbon, modified tar, binder, micropore volume, gas phase adsorption

中图分类号:

TQ35
TQ424

徐茹婷, 马名哲, 应浩, 孙昊, 金彦任, 赵婷. 竹热解气化副产物改性制备高性能成型活性炭及其表征[J]. 林产化学与工业, 2023, 43(4): 1-8.

Ruting XU, Mingzhe MA, Hao YING, Hao SUN, Yanren JIN, Ting ZHAO. Preparation and Characterization of High Performance Formed Activated Carbon by Modification of By-products from Bamboo Gasification[J]. Chemistry and Industry of Forest Products, 2023, 43(4): 1-8.

参考文献 22

1	张云洁, 蔡昌杨, 冉取丙, 等. 竹子遗传改良技术研究进展[J]. 世界林业研究, 2021, 34 (5): 26- 31.
	ZHANG Y J , CAI C Y , RAN Q B , et al. Research progress in bamboo breeding and genetic improvement[J]. World Forestry Research, 2021, 34 (5): 26- 31.
2	许伟, 孙康, 缪存标, 等. 水蒸气活化制备竹质成型活性炭及其对二硫化碳的吸附性能[J]. 林业工程学报, 2018, 3 (2): 40- 46.
	XU W , SUN K , MIAO C B , et al. Preparation of bamboo molding activated carbon by steam activation and its adsorption performance on carbon disulfide[J]. Journal of Forestry Engineering, 2018, 3 (2): 40- 46.
3	应浩, 蒋剑春. 生物质能源转化技术与应用(Ⅳ)——生物质热解气化技术研究和应用[J]. 生物质化学工程, 2007, 41 (6): 47- 55.
	YING H , JIANG J C . Conversion technology and utilization of biomass energy(Ⅳ)——Technology and application of biomass gasification[J]. Biomass Chemical Engineering, 2007, 41 (6): 47- 55.
4	ZHANG G X , CHEN Y M , CHEN Y G , et al. Activated biomass carbon made from bamboo as electrode material for supercapacitors[J]. Materials Research Bulletin, 2018, 102, 391- 398. doi: 10.1016/j.materresbull.2018.03.006
5	PAN H Y , ZHAO J Y , LIN Q , et al. Preparation and characterization of activated carbons from bamboo sawdust and its application for CH₄ selectivity adsorption from a CH₄/N₂ system[J]. Energy & Fuels, 2016, 30 (12): 10730- 10738.
6	TAIWO A F , CHINYERE N J . Sorption characteristics for multiple adsorption of heavy metal ions using activated carbon from Nigerian bamboo[J]. Journal of Materials Science & Chemical Engineering, 2016, 4, 39- 48.
7	吴奥. 竹材热解及竹炭活化特性研究[D]. 哈尔滨: 哈尔滨工业大学, 2020.
	WU A. Study on bamboo pyrolysis and bamboo charcoal activation characteristics[D]. Harbin: Harbin Institute of Technology, 2020.
8	应伟军, 钟金环, 赵柯豫, 等. 水蒸气法刺竹活性炭的制备工艺及性能表征[J]. 竹子学报, 2020, 39 (3): 67- 72.
	YING W J , ZHONG J H , ZHAO K Y , et al. Preparation and characterization of activated carbon from Bambusa blumeana Schult.f with steam method[J]. Journal of Bamboo Research, 2020, 39 (3): 67- 72.
9	杨华, 黄丽, 刘石彩, 等. 竹屑热解过程及产物特征研究[J]. 太阳能学报, 2017, 38 (5): 1431- 1439.
	YANG H , HUANG L , LIU S C , et al. Study on bamboo pyrolysis process and product characteristics[J]. Acta Energiae Solaris Sinica, 2017, 38 (5): 1431- 1439.
	MILNE T A, EVANS R J, ABATZAGLOU N. Biomass gasifier "tars": Their nature, formation, and conversion: NREL/TP-570-25357[R]. Golden: National Renewable Energy Laboratory, 1998.
11	TONG S M , FENG M G . Aphidicidal activity of a novel botanical insecticide made by alkalization of bamboo tar[J]. Crop Protection, 2016, 87, 85- 89.
12	蒋应梯, 庄晓伟, 潘炘, 等. 竹材加工剩余物制复合型蜂窝活性炭试验研究[J]. 竹子研究汇刊, 2019, (1): 58- 62.
	JIANG Y T , ZHUANG X W , PAN X , et al. Manufacture of compound honeycomb-like activated carbon from bamboo processing residues[J]. Journal of Bamboo Research, 2019, (1): 58- 62.
13	陈冠益, 刘聪, 颜蓓蓓, 等. 生物质焦油热解动力学分析[J]. 太阳能学报, 2016, 37 (3): 529- 534.
	CHEN G Y , LIU C , YAN B B , et al. Kinetic analysis of corn-cob tar pyrolysis[J]. Acta Energiae Solaris Sinica, 2016, 37 (3): 529- 534.
14	蒋文静. 竹焦油基耐高温胶粘剂的制备与性能研究[D]. 北京: 北京化工大学, 2016.
	JIANG W J. The preparation and performance of a heat resistant adhesive from bamboo[D]. Beijing: Beijing University of Chemical Technology, 2016.
15	王佳讯. 竹焦油基酚醛树脂的制备及性能研究[D]. 杭州: 浙江工业大学, 2012.
	WANG J X. Preparation and characterization of bamboo tar-based phenolic resin[D]. Hangzhou: Zhejiang University of Technology, 2012.
16	杨燕红, 孙鸣, 刘媛媛, 等. 酚醛树脂改性煤焦油沥青的热解特性[J]. 煤炭转化, 2016, 39 (1): 62- 66.
	YANG Y H , SUN M , LIU Y Y , et al. Pyrolysis characteristics of coal tar pitch modified by phenolic resin[J]. Coal Conversion, 2016, 39 (1): 62- 66.
17	吴艳, 马博文, 钟金龙. 不同类型重油中碱性氮化合物分子组成及其加氢裂化转化规律[J]. 煤炭学报, 2019, 44 (4): 1232- 1238.
	WU Y , MA B W , ZHONG J L . Composition analysis of basic nitrogen compounds in different heavy oils[J]. Journal of China Coal Society, 2019, 44 (4): 1232- 1238.
18	隆建. 掺炼高温煤焦油提高劣质渣油溶剂脱沥青效果及机理研究[D]. 上海: 华东理工大学, 2012.
	LONG J. Research on improving effect and mechanism of solvent deasphalting of the inferior vacuum residue by blend with high temperature coal tar[D]. Shanghai: East China University of Science and Technology, 2012.
19	许伟, 刘军利, 邓先伦, 等. 生物质气化剩余炭粉制备成型活性炭性能研究[J]. 林产化学与工业, 2020, 40 (5): 91- 98.
	XU W , LIU J L , DENG X L , et al. Preparation of formed activated carbon based on residual carbon powder from biomass gasification[J]. Chemistry and Industry of Forest Products, 2020, 40 (5): 91- 98.
20	许钦一. 高比表面积成型活性炭的制备及其性能研究[D]. 大连: 大连理工大学, 2010.
	XU Q Y. Preparation and properties of activated carbon monoliths with high specific surface area[D]. Dalian: Dalian University of Technology, 2010.
21	蒋剑春, 孙康. 活性炭制备技术及应用研究综述[J]. 林产化学与工业, 2017, 37 (1): 1- 13.
	JIANG J C , SUN K . Review on preparation technology of activated carbon and its application[J]. Chemistry and Industry of Forest Products, 2017, 37 (1): 1- 13.
22	徐茹婷, 卢辛成, 许伟, 等. 磷酸法玉米秸秆基活性炭的制备及其表征[J]. 生物质化学工程, 2022, 56 (1): 1- 6.
	XU R T , LU X C , XU W , et al. Preparation and characterization of corn straw based activated carbon by phosphoric acid activation[J]. Biomass Chemical Engineering, 2022, 56 (1): 1- 6.

[1]	许伟,刘军利,邓先伦,孙云娟,许玉,刘光华. 生物质气化剩余炭粉制备成型活性炭性能研究[J]. 林产化学与工业, 2020, 40(5): 91-98.
[2]	许伟, 刘军利, 缪存标, 孙康, 宋曜光. 乙基纤维素包覆成型活性炭的制备及其性能研究[J]. 林产化学与工业, 2017, 37(2): 49-56.
[3]	黄明堦, 黄碧珠, 林珊, 黄彪, 陈燕丹. 糯米灰浆粘结型富钙成型活性炭的制备及其性能[J]. 林产化学与工业, 2016, 36(6): 16-22.
[4]	程婷;陈杰;黄祥;蒋文举;郭家秀;. 核桃壳脱硫活性炭成型工艺研究[J]. 林产化学与工业, 2013, 33(4): 48-52.
[5]	卢辛成;蒋剑春;孟中磊;孙康;谢新苹. 生物质成型炭的制备及其性能研究[J]. 林产化学与工业, 2013, 33(2): 81-84.
[6]	王锐;陈华;刘守新. CMC粘接法制备柱状成型活性炭[J]. 林产化学与工业, 2011, 31(5): 6-10.

竹热解气化副产物改性制备高性能成型活性炭及其表征

Preparation and Characterization of High Performance Formed Activated Carbon by Modification of By-products from Bamboo Gasification

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