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林产化学与工业

林产化学与工业 ›› 2012, Vol. 32 ›› Issue (3): 126-130.

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α-蒎烯氧化中的催化作用研究进展

郑敏1, 何必飞2, 俆琼2, 尹笃林2   

  1. 1. 湖南第一师范学院 湖南 长沙 410205;2. 化学生物学及中药分析教育部重点实验室; 湖南师范大学 精细催化合成研究所 湖南 长沙 410081
  • 收稿日期:2011-08-05 修回日期:1900-01-01 出版日期:2012-06-30 发布日期:2012-06-30
  • 通讯作者: 尹笃林,教授,博士生导师,研究领域为催化与生物质转化;E-mail:dulinyin@126.com.

Investigation on the Catalysis in the Oxidation of α-Pinene

ZHENG Min1, HE Bi-fei2, XU Qiong2, YIN Du-lin2   

  1. 1. Hunan First Normol University, Changsha 410205, China;2. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education;Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081, China
  • Received:2011-08-05 Revised:1900-01-01 Online:2012-06-30 Published:2012-06-30

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摘要： 概述了近20年来国内外对催化α-蒎烯氧化反应过程的研究,重点分析了α-蒎烯氧化中催化剂的性能特点及产物分布规律,总结了过渡金属盐、氧化物、配合物、分子筛及杂多酸在α-蒎烯氧化中的催化作用,比较了催化活性及选择性的特点,并初步探讨了发展趋势。提出在已有的α-蒎烯氧化反应催化剂中,分子筛类催化剂在制备方法和工业化发展上有一定的优势,深入研究过渡金属化合物在α-蒎烯氧化反应的催化性能及调变方法,应是α-蒎烯氧化反应中值得重点关注的研究内容。

关键词: α-蒎烯, 催化剂, 氧化反应

Abstract: The catalysis in the oxidation of α-pinene during the last two decades was reviewed. The catalysis of transition-metal salts, oxides, coordination compounds, zeolites and heteropoly acids for the reactions were presented. The activity and selectivity of these catalysts were compared. It is emphasized that the innovation in the catalytic oxidation of α-pinene should be focused on improving the atom economy. The catalytic properties and modifications of transition-metal compounds for the reaction should be deeply investigated. The development of industrial equipments and processes should be concerned.

Key words: α-pinene, catalyst, oxidation

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