羟基氢化松香衍生物改性氟碳涂料的制备及性能研究

doi:10.3969/j.issn.0253-2417.2023.06.010

Abstract

Abstract:

To improve the low hardness and poor adhesion of fluorocarbon coatings, and expand their further application in the marine antifouling field, hydroxyl hydrogenated rosin derivative was synthesized by reacting renewable resource hydrogenated rosin with epichlorohydrin. The structure of the derivative was characterized using acid value, hydroxyl value determination, as well as GC-MS and FT-IR techniques. The obtained product was used to modify fluorocarbon coatings, and the influence for the addition amount of hydroxyl hydrogenated rosin derivative on the performance of the modified fluorocarbon coatings was studied. The results showed that hydroxyl hydrogenated rosin derivative was a mixture of 3-hydrogenated rosin acyloxy-2-hydroxypropyl chloride and 3-hydrogenated rosin acyloxy-1, 2-dihydroxy-propane. The acid value of derivative was 4.7 mg/g, and the hydroxyl value was 243.1 mg/g. With the increase of hydroxyl hydrogenated rosin derivative amount, the drying time, the pencil hardness and the adhesion strength of the modified fluorocarbon coatings increased, and the flexibility and impact resistance met the standard requirements. The coatings also exhibit good acid and alkali resistance(no abnormalities was found after it was immersed in acid and alkali solutions for 10 days). When the addition of the hydroxyl hydrogenated rosin derivative was 15%, the comprehensive performance of the coating was optimal, with drying time of 5.8 minutes, pencil hardness of 4H, coating adhesion strength of 15.5 MPa, and qualified results for 2 mm shaft bending and 50 cm impact test.

Key words: hydrogenated rosin, epichlorohydrin, fluorocarbon coating, biomass, corrosion

CLC Number:

TQ35

Wen QI, Yajing HU, Xingwei LI, Man QIN, Chun LU. Preparation and Properties of Fluorocarbon Coatings Modified by Hydroxyl Hydrogenated Rosin Derivative[J]. Chemistry and Industry of Forest Products, 2023, 43(6): 74-80.

Figures/Tables 6

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Table 1

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Table 2

References 22

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样品 sample	酸值acid value /(mg·g^-1)		羟值hydroxyl value /(mg·g^-1)
样品 sample	理论值 theoretical value	实测值 measured value	理论值 theoretical value	实测值 measured value
氢化松香hydrogenated rosin	182.7~185.1	166.9	0	0
3-氢化松香酰氧-2-羟丙基氯3-hydrogenated rosin acyloxy-2-hydroxypropyl chloride	0		140.0
3-氢化松香酰氧-1, 2-二羟基丙二醇3-hydrogenated rosin acyloxy-1, 2-dihydroxypropylene glycol	0		293.1
氢化松香衍生物hydrogenated rosin derivative		4.7		243.1
氟碳树脂fluorocarbon resin		3.7		16.6

添加量/% dosage	表干时间/min surface drying time	铅笔硬度 pencil hardness	附着力/MPa adhesion	柔韧性/mm flexibility	抗冲击性/cm impact strength
0	4.6	2H	—	2	50
5	5.4	3H	12.8	2	50
10	5.7	3H	14.4	2	50
15	5.8	4H	15.5	2	50
20	11.6	4H	16.7	2	50
50	19.2	4H	19.7	2	50

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Preparation and Properties of Fluorocarbon Coatings Modified by Hydroxyl Hydrogenated Rosin Derivative

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