低共熔溶剂应用于木质纤维素预处理的研究进展

doi:10.3969/j.issn.0253-2417.2023.06.017

Abstract

Abstract:

Deep eutectic solvent(DES) was a new type of green solvent, which was simple preparation, low cost, non-toxic, biodegradable, recyclable, etc, and had broad prospects in the application of lignocellulose pretreatment. In this paper, the composition, classification, preparation methods and physicochemical properties of DES were summarized. Subsequently, the research and application of DES in the field of biomass pretreatment were reviews. The mechanistic of DES pretreatment and separation of lignocellulose were concluded. The application progress of DES selectively separating lignocellulose was mainly introduced in order to provide theoretical reference for large-scale application of DES in pretreatment of lignocellulosic biomass.

Key words: deep eutectic solvents, lignocellulose, pretreatment, selective separation

CLC Number:

TQ35

Shuheng ZHAO, Zhuojie LI, Jianjun HU, Sen YAO, Wei WANG. Research Progress on the Application of Deep Eutectic Solvent in Lignocellulose Pretreatment[J]. Chemistry and Industry of Forest Products, 2023, 43(6): 130-138.

Figures/Tables 4

Table 1

Fig.1

Fig.2

Fig.3

References 58

1	谭家能. 低共熔溶剂及天然产物绿色提取[M]. 北京: 中国农业科学技术出版社, 2021.
	TAN J N . Low Eutectic Solvent and Green Extraction of Natural Products[M]. Beijing: China Agricultural Science and Technology Press, 2021.
2	LOOW Y L , WU T Y , TAN K A , et al. Recent advances in the application of inorganic salt pretreatment for transforming lignocellulosic biomass into reducing sugars[J]. Journal of Agricultural and Food Chemistry, 2015, 63 (38): 8349- 8363. doi: 10.1021/acs.jafc.5b01813
3	ABBOTT A P , CAPPER G , DAVIES D L , et al. Novel solvent properties of choline chloride/urea mixtures[J]. Chemical Communications, 2003, 9 (1): 70- 71.
4	司马国宝, 王帅, 崔莹, 等. 低共熔溶剂对木质纤维素分离及木质素提取的研究进展[J]. 现代化工, 2019, 39 (9): 26- 30.
	SIMA G B , WANG S , CUI Y , et al. Research progress in lignocellulose separation and lignin extraction by deep eutectic solvents[J]. Modern Chemical Industry, 2019, 39 (9): 26- 30.
5	SHEN Y , SUN J K , YI Y X , et al. One-pot synthesis of levulinic acid from cellulose in ionic liquids[J]. Bioresource Technology, 2015, 192, 812- 816. doi: 10.1016/j.biortech.2015.05.080
6	ZHANG Q H , VIGIER K D , ROYER S , et al. Deep eutectic solvents: Syntheses, properties and applications[J]. Chemical Society Reviews, 2012, 41 (21): 7108- 7146. doi: 10.1039/c2cs35178a
7	KUMAR N, MULEY P D, BOLDOR D, et al. Pretreatment of waste biomass in deep eutectic solvents: Conductive heating versus microwave heating[J/OL]. Industrial Crops and Products, 2019, 142: 111865[2022-05-07]. https://doi.org/10.1016/j.indcrop.2019.111865.
8	黄一波, 蒋磊. 低共熔溶剂在天然产物萃取中的应用进展[J]. 化学试剂, 2022, 44 (1): 10- 20.
	HUANG Y B , JIANG L . Application progress of deep eutectic solvent(DES) in natural products extraction[J]. Chemical Reagents, 2022, 44 (1): 10- 20.
9	李利芬, 吴志刚, 梁坚坤, 等. 低共熔溶剂在木质纤维类生物质研究中的应用[J]. 林业工程学报, 2020, 5 (4): 20- 28.
	LI L F , WU Z G , LIANG J K , et al. Application of deep eutectic solvents in lignocellulosic biomass processing[J]. Journal of Forestry Engineering, 2020, 5 (4): 20- 28.
10	ABBOTT A P , BARRON J C , RYDER K S , et al. Eutectic-based ionic liquids with metal-containing anions and cations[J]. Chemistry, 2007, 13 (22): 6495- 6501. doi: 10.1002/chem.200601738
11	汪心娉, 余璟, 朱瑞琦, 等. 低共熔溶剂选择性溶解木质纤维原料的研究进展[J]. 中国造纸学报, 2021, 36 (2): 79- 86.
	WANG X P , YU J , ZHU R Q , et al. Research progress on selective dissolution of lignocellulosic materials in deep eutectic solvents[J]. Transactions of China Pulp and Paper, 2021, 36 (2): 79- 86.
12	SMITH E L , ABBOTT A P , RYDER K S . Deep eutectic solvents(DESs)and their applications[J]. Chemistry Reviews, 2014, 114 (21): 11060- 11082. doi: 10.1021/cr300162p
13	张筱仪, 刘慰, 刘华玉, 等. 基于低共熔溶剂的木质纤维生物质预处理及其高值化利用的研究进展[J]. 中国造纸, 2020, 39 (8): 85- 93.
	ZHANG X Y , LIU W , LIU H Y , et al. Research advances of pretreatment and high value utilization of lignocellulosic biomass based on deep eutectic solvents[J]. China Pulp & Paper, 2020, 39 (8): 85- 93.
14	金永香, 刘天勤, 顾忠基, 等. 氯化胆碱/丙三醇低共熔溶剂改性木质素磺酸钠及其在环氧树脂乳液中的应用[J]. 林业工程学报, 2017, 2 (4): 96- 102.
	JIN Y X , LIU T Q , GU Z J , et al. Modification of sodium lignosulfonate with ChCl/glycerol deep-eutectic solvent and itsapplication to epoxy resin emulsion[J]. Journal of Forestry Engineering, 2017, 2 (4): 96- 102.
15	刘天勤, 连海兰, 洪枢, 等. 氯化胆碱/尿素低共熔溶剂改性木质素的环氧固化体系[J]. 东北林业大学学报, 2018, 46 (4): 78-82, 87.
	LIU T Q , LIAN H L , HONG S , et al. Effect of modified lignin by choline chloride/urea deep-eutectic solvent on curing properties of epoxy resin[J]. Journal of Northeast Forestry University, 2018, 46 (4): 78-82, 87.
16	赵天畅, 王杰, 侯海旭, 等. 三元低共熔溶剂高效预处理提高杨木酶水解效率[J]. 林业工程学报, 2022, 7 (3): 86- 92.
	ZHAO T C , WANG J , HOU H X , et al. The efficient pretreatment with ternary-deep eutectic solvent for facilitating the enzymatichydrolysis of poplar[J]. Journal of Forestry Engineering, 2022, 7 (3): 86- 92.
17	ABO-HAMAD A , HAYYAN M , ALSAADI M A , et al. Potential applications of deep eutectic solvents in nanotechnology[J]. Chemical Engineering Journal, 2015, 273, 551- 567. doi: 10.1016/j.cej.2015.03.091
18	TANG B , ROW K H . Recent developments in deep eutectic solvents in chemical sciences[J]. Monatshefte Für Chemie: Chemical Monthly, 2013, 144 (10): 1427- 1454. doi: 10.1007/s00706-013-1050-3
19	SHAHBAZ K , MJALLI F S , HASHIM M A , et al. Prediction of the surface tension of deep eutectic solvents[J]. Fluid Phase Equilibria, 2012, 319, 48- 54. doi: 10.1016/j.fluid.2012.01.025
20	ABBOTT A P , HARRIS R C , RYDER K S . Application of hole theory to define ionic liquids by their transport properties[J]. The Journal of Physical Chemistry B, 2007, 111 (18): 4910- 4913. doi: 10.1021/jp0671998
21	ABBOTT A P , CAPPER G , GRAY S . Design of improved deep eutectic solvents using hole theory[J]. ChemPhysChem, 2006, 7 (4): 803- 806. doi: 10.1002/cphc.200500489
22	ABBOTT A P , CAPPER G , DAVIES D L , et al. Ionic liquids based upon metal halide/substituted quaternary ammonium salt mixtures[J]. Inorganic Chemistry, 2004, 43 (11): 3447- 3452. doi: 10.1021/ic049931s
23	HOU Y W , GU Y Y , ZHANG S M , et al. Novel binary eutectic mixtures based on imidazole[J]. Journal of Molecular Liquids, 2008, 143 (2/3): 154- 159.
24	SHAHBAZ K , BAROUTIAN S , MJALLI F S , et al. Densities of ammonium and phosphonium based deep eutectic solvents: Prediction using artificial intelligence and group contribution techniques[J]. Thermochimica Acta, 2012, 527, 59- 66. doi: 10.1016/j.tca.2011.10.010
25	SHAHBAZ K , MJALLI F S , HASHIM M A , et al. Using deep eutectic solvents based on methyl triphenyl phosphunium bromide for the removal of glycerol from palm-oil-based biodiesel[J]. Energy Fuels, 2011, 25 (6): 2671- 2678. doi: 10.1021/ef2004943
26	谢宜彤, 郭鑫, 吕艳娜, 等. 低共熔溶剂在木质纤维原料溶解及其组分分离中的研究进展[J]. 林产化学与工业, 2019, 39 (5): 11- 18.
	XIE Y T , GUO X , LYU Y N , et al. Research progress on the dissolution of lignocellulose and separation of its componentsby deep eutectic solvents[J]. Chemistry and Industry of Forest Products, 2019, 39 (5): 11- 18.
27	REICHARDT C , WELTON T . Solvents and solvent effects in organic chemistry[M]. Weinheim: Wiley-VCH, 2004: 97- 103.
28	XU P , CHENG J , LOU W Y , et al. Using deep eutectic solvents to improve the resolution of racemic 1-(4-methoxyphenyl) ethanol through Acetobacter sp. CCTCC M209061 cell-mediated asymmetric oxidation[J]. RSC Advances, 2014, 5 (9): 6357- 6364.
29	ZHAO B Y , XU P , YANG F X , et al. Biocompatible deep eutectic solvents based on choline chloride: Characterization and application to the extraction of rutin from sophora japonica[J]. ACS Sustainable Chemistry & Engineering, 2015, 3 (11): 2746- 2755.
30	BRANDT A , GRASVIK J , HALLETT J P , et al. Deconstruction of lignocellulosic biomass with ionic liquids[J]. Green Chemistry, 2013, 15 (3): 550- 583. doi: 10.1039/c2gc36364j
31	徐环斐, 彭建军, 孔毅, 等. DES在木质纤维素类生物质预处理领域的研究进展[J]. 中华纸业, 2020, 41 (8): 22- 29. doi: 10.3969/j.issn.1007-9211.2020.08.003
	XU H F , PENG J J , KONG Y , et al. A review on deep eutectic solvent(DES) pretreatment of lignocellulosic biomass[J]. China Pulp & Paper Industry, 2020, 41 (8): 22- 29. doi: 10.3969/j.issn.1007-9211.2020.08.003
32	FRANCISCO M , VAN DEN BRUINHORST A V , KROON M C , et al. New natural and renewable low transition temperature mixtures(LTTMs): Screening as solvents for lignocellulosic biomass processing[J]. Green Chemistry, 2012, 14 (8): 2153- 2157. doi: 10.1039/c2gc35660k
33	陈子澍, 赵子暄, 张绍蒙, 等. 季铵盐/酰胺类低共熔溶剂的制备及其对纤维素的溶解性能[J]. 林产化学与工业, 2018, 38 (5): 93- 99.
	CHEN Z S , ZHAO Z X , ZHANG S M , et al. Effect of hydrogen bonding of ammonium-based deep eutectic solvents on cellulose dissolution[J]. Chemistry and Industry of Forest Products, 2018, 38 (5): 93- 99.
34	HOU X D , LI A L , LIN K P , et al. Insight into the structure-function relationships of deep eutectic solvents during rice straw pretreatment[J]. Bioresource Technology, 2018, 249, 261- 267. doi: 10.1016/j.biortech.2017.10.019
35	ALVAREZ-VASCO C , MA R , QUINTERO M , et al. Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents(DES): A source of lignin for valorization[J]. Green Chemistry, 2016, 18 (19): 5133- 5141. doi: 10.1039/C6GC01007E
36	王冬梅. 低共熔溶剂分离木质纤维素及纤维素组分的利用[D]. 北京: 北京化工大学, 2018.
	WANG D M. Fractionation of lignocellulose withdeepeutectic solvent and comprehensiveutilization of its cellulose components[D]. Beijing: Beijing University of Chemical Technology, 2018.
37	常杰, 刘钧, 郭姝君, 等. 新型深度共熔溶剂选择性分离木质素的研究[J]. 华南理工大学学报(自然科学版), 2016, 44 (6): 14-20, 26. doi: 10.3969/j.issn.1000-565X.2016.06.003
	CHANG J , LIU J , GUO S J , et al. Investigation into selective separation of lignin in novel deep eutectic solvent[J]. Journal of South China University of Technology(Natural Science Edition), 2016, 44 (6): 14-20, 26. doi: 10.3969/j.issn.1000-565X.2016.06.003
38	刘金科, 杨桂花, 齐乐天, 等. 胆碱类低共熔溶剂选择性分离杨木中木质素的研究[J]. 中国造纸, 2020, 39 (4): 1- 9.
	LIU J K , YANG G H , QI L T , et al. Selective extraction of poplar lignin with choline-based deep eutectic solvents[J]. China Pulp & Paper, 2020, 39 (4): 1- 9.
39	TANG X , ZUO M , LI Z , et al. Green processing of lignocellulosic biomass and its derivatives in deep eutectic solvents[J]. ChemSusChem, 2017, 10 (13): 2696- 2706. doi: 10.1002/cssc.201700457
40	LIU Y Z , CHEN W S , XIA Q Q , et al. Efficient cleavage of lignin carbohydrate complexes and ultrafast extraction of lignin oligomers from wood biomass by microwave-assisted treatment with deep eutectic solvent[J]. ChemSusChem, 2017, 10 (8): 1692- 1700. doi: 10.1002/cssc.201601795
41	董艳梅, 安艳霞, 马阳阳, 等. 深度共熔溶剂预处理木质纤维素生物质研究进展[J]. 化工进展, 2021, 40 (3): 1594- 1603.
	DONG Y M , AN Y X , MA Y Y , et al. Research progress on deep eutectic solvent of lignocellulose pretreatment[J]. Chemical Industry and Engineering Progress, 2021, 40 (3): 1594- 1603.
42	PROCENTESE A , JOHNSON E , ORR V , et al. Deep eutectic solvent pretreatment and subsequent saccharification of corncob[J]. Bioresource Technology, 2015, 192, 31- 36. doi: 10.1016/j.biortech.2015.05.053
43	XU G C , DING J C , HAN R Z , et al. Enhancing cellulose accessibility of corn stover by deep eutectic solvent pretreatment for butanol fermentation[J]. Bioresource Technology, 2016, 203, 364- 369. doi: 10.1016/j.biortech.2015.11.002
44	HOU X D , FENG G J , YE M , et al. Significantly enhanced enzymatic hydrolysis of rice straw via a high-performance two-stage deep eutectic solvents synergistic pretreatment[J]. Bioresource Technology, 2017, 238, 139- 146. doi: 10.1016/j.biortech.2017.04.027
45	YU Q , ZHANG A M , WANG W , et al. Deep eutectic solvents from hemicellulose-derived acids for the cellulosic ethanol refining of Akebia' herbal residues[J]. Bioresource Technology, 2018, 247, 705- 710. doi: 10.1016/j.biortech.2017.09.159
46	ZULKEFLI S , ABDULMALEK E , RAHMAN M B A . Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk[J]. Renewable Energy, 2017, 107, 36- 41. doi: 10.1016/j.renene.2017.01.037
47	SHARMA M , MUKESH C , MONDAL D , et al. Dissolution of α-chitin in deep eutectic solvents[J]. RSC Advances, 2013, 3 (39): 18149- 18155. doi: 10.1039/c3ra43404d
48	ABBOTT A , CAPPER G , GRAY S , et al. Design of improved deep eutectic solvents using hole theory[J]. ChemPhysChem, 2010, 7 (4): 803- 806.
49	李利芬, 胡英成. 乙酰化木质素磺酸盐的制备及表征[J]. 高分子材料科学与工程, 2015, 31 (1): 164- 169.
	LI L F , HU Y C . Preparation and characterization of acetylated lignosulfonate[J]. Polymer Materials Science & Engineering, 2015, 31 (1): 164- 169.
50	KIM K H , DUTTA T , SUN J , et al. Biomass pretreatment using deep eutectic solvents from lignin derived phenols[J]. Green Chemistry, 2018, 20 (4): 809- 815. doi: 10.1039/C7GC03029K
51	SIRVIOÖ J A , VISANK O M , LⅡMATAINEN H . Deep eutectic solvent system based on choline chloride-urea as a pre-treatment for nanofibrillation of wood cellulose[J]. Green Chemistry, 2015, 17 (6): 3401- 3406.
52	SIRVIOÖ J A , VISANK O M , LⅡMATAINEN H . Acidic deep eutectic solvents as hydrolytic media for cellulose nanocrystal production[J]. Biomacromolecules, 2016, 17 (9): 3025- 3032.
53	SIRVIOO J A , UKKOLA J , LⅡMATAINEN H . Direct sulfation of cellulosefibers using a reactive deep eutectic solvent to produce highly charged cellulose nanofibers[J]. Cellulose, 2019, 26 (4): 2303- 2316.
54	周敏姑, 郭英杰, 郝子越, 等. 氯化胆碱/乳酸低共熔溶剂预处理对杨木酶水解特性的影响[J]. 西北农林科技大学学报(自然科学版), 2020, 48 (12): 55- 63.
	ZHOU M G , GUO Y J , HAO Z Y , et al. Effects of choline chloride/lactic acid deep eutectic solvents pretreatment onenzymatic hydrolysis of poplar[J]. Journal of Northwest A & F University(Natural Science Edition), 2020, 48 (12): 55- 63.
55	陈鑫东, 熊莲, 黎海龙, 等. 低共熔溶剂在木质纤维素预处理促进酶水解效率的研究进展[J]. 新能源进展, 2019, 7 (5): 415- 422.
	CHEN X D , XIONG L , LI H L , et al. Research progress of deep eutectic solvent in lignocellulose pretreatment to promoteEnzymatic hydrolysis efficiency[J]. Advances in New and Renewable Energy, 2019, 7 (5): 415- 422.
56	HUANG C , ZHAO C , LI H L , et al. Comparison of different pretreatments on the synergistic effect of cellulase and xylanase during the enzymatic hydrolysis of sugarcane bagasse[J]. RSC advances, 2018, 8 (54): 30725- 30731.
57	丁纪财. 玉米秸秆的离子液体预处理及其在丁醇发酵中的应用研究[D]. 无锡: 江南大学, 2016.
	DING J C. Pretreatment of corn stover by ionic liquids and its application in butanol fermentation[D]. Wuxi: Jiangnan University, 2016.
58	GUO Z, ZHANG Q, YOU T, et al. Heteropoly acids enhanced neutral deep eutectic solvent pretreatment for enzymatic hydrolysis and ethanol fermentation of Miscanthus×giganteus under mild conditions[J/OL]. Bioresource Technology, 2019, 293(29): 122036

低共熔溶剂¹⁾ deep eutectic solvents	物质的量之比 molar ratio	熔点/℃ melting point	密度/(g·cm^-3) density	黏度/(mPa·s) viscosity	表面张力/(mN·m^-1) surface tension	电导率/(S·m^-1) conductivity	参考文献 references
ChCl-尿素 ChCl-urea	1∶2	12	1.25	750(25 ℃)	52.00	7.5(25 ℃)	[17]
ChCl-甘油 ChCl-glycerol	1∶3	-32.65	1.20	450(20 ℃)			[17]
ChCl-甘油 ChCl-glycerol	1∶2	-36.15	1.18	259(25 ℃)	57.24	10.5(25 ℃)	[17-18]
ChCl-乙二醇 ChCl-ethylene glycol	1∶2	-66.01	1.12	37(25 ℃)	48.91	76.1(25 ℃)	[19]
ChCl-1, 4丁二醇 ChCl-1, 4-butylene glycol	1∶3	-32	1.06	140(25 ℃)	47.17	16.4(20 ℃)	[19-20]
ChCl-2, 2, 2-三氟乙酰胺 ChCl-2, 2, 2-trifluoroacetamide	1∶2		1.342	77(40 ℃)	35.9	2.86(40 ℃)	[21]
乙胺盐酸盐-尿素 ethylamine hydrochloride-urea	1∶1.5		1.14	128(40 ℃)	52.9	3.48(40 ℃)	[21]
ChCl-氯化锌 ChCl-ZnCl₂	1∶2			85 000(25 ℃)		6(42 ℃)	[22]
ZnCl₂-尿素 ZnCl₂-urea	1∶3.5		1.63	11 340(25 ℃)		1.8(42 ℃)	[23]
甲基三苯基溴化膦-乙二醇 methyltriphenylphosphonium bromide-ethylene glycol	1∶4	-49.32	1.23		51.29		[24]
甲基三苯基溴化膦-三甘醇 methyltriphenylphosphonium bromide-triethylene glycol	1∶5	-21	1.19		49.58		[25]

[1]	Gaoyuan LIU, Zhengjun SHI, Ping ZHAO, Haiyan YANG, Jing YANG. Effects of Sulfuric Acid on Enzymatic Hydrolysis and Fermentation of Hydrogen Peroxide-acetic Acid Pretreated Dendrocalamus sinicus [J]. Chemistry and Industry of Forest Products, 2023, 43(5): 109-116.
[2]	Yaqian LIU, Jin WANG, Feng TANG. Optimization of Extraction Process of Flavone C-glycosides from Bamboo Leaves by Deep Eutectic Solvent-Ball Mill Method [J]. Chemistry and Industry of Forest Products, 2023, 43(4): 60-66.
[3]	Bo ZHANG, Xiang LI, Wei LIU, Xiaoli LI. Synthesis and Electrochemical Properties of Biomass Mesoporous Carbon Doped with Nitrogen and Phosphorus [J]. Chemistry and Industry of Forest Products, 2023, 43(2): 56-62.
[4]	Shunhui TAO, Kexuan ZHANG, Biying LI, Xiaojie ZHENG, Yao LIU, Xiaoqing LIN. Enzymatic Digestibility of Ternary Deep Eutectic Solvent Pretreated Sugarcane Bagasse [J]. Chemistry and Industry of Forest Products, 2023, 43(2): 135-142.
[5]	Qin CHENG, Juanzhang SHEN, Yanyan CAI, Jun YE, Ziyang WU, Weihong TAN. Carbon Stable Isotope Fractionation of 5-Hydroxymethylfurfural from Hydrothermal Liquefaction [J]. Chemistry and Industry of Forest Products, 2023, 43(1): 63-71.
[6]	Huiyang BIAN, Sheng DUAN, Jin WU, Liulian HUANG, Shuangquan YAO, Hongqi DAI. Preparation and Properties of Lignocellulosic Nanofibrils Obtained by Polycarboxylic Acid Pretreatments [J]. Chemistry and Industry of Forest Products, 2022, 42(6): 11-16.
[7]	Xiaoyan CHEN, Rongqing ZHANG, Yating JIAN, Qiang YU, Zhongming WANG, Zhenhong YUAN. Analysis of Enzymatic Hydrolysis Process of High-solid Lignocellulose Materials [J]. Chemistry and Industry of Forest Products, 2022, 42(4): 61-67.
[8]	Tengfei MA, Yawei ZHAN, Yue LIU, Zhiqiang LI. Formaldehyde/Dioxane Pretreatment on Bamboo for Producing Monosaccharide and Lactic Acid [J]. Chemistry and Industry of Forest Products, 2022, 42(4): 101-106.
[9]	Fang WANG, Hongdan ZHANG. Application of Aspen Plus in Lignocellulosic Biomass Pretreatment for Ethanol Production: A Review [J]. Chemistry and Industry of Forest Products, 2022, 42(4): 119-130.
[10]	Yifei DU, Yue PU, Liping ZHANG, Qiang ZHAO, Xianliang SONG. Power Generation Performance of Lignin in Direct Biomass Fuel Cell [J]. Chemistry and Industry of Forest Products, 2022, 42(3): 75-82.
[11]	Xiaoyan YIN, Tingting CAI, Chao LIU, Jianchun JIANG, Kui WANG. Directional Decomposition of Bamboo Powder in Bio-based Polar Aprotic Solvent/Aqueous p-Toluenesulfonic Acid Coupling Systems [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 1-9.
[12]	Yan WU, Zhongjian TIAN, Jiachuan CHEN, Fengshan ZHANG, Guigan FANG, Xingxiang JI. Hydrolysis Kinetics of Poplar During Thermal Hydrolysis [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 21-28.
[13]	Shujie WANG, Xianfeng HOU, Yingshi HUANG, Xiaofeng CHEN, Jin SUN, Zhenzhong GAO. Effect of Alkaline Ionic Liquid TBAH Pretreatment on Structure and Enzymatic Properties of Eucalyptus [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 57-63.
[14]	Feng YU, Zhihong WANG, Guangyao ZHANG, Zhiyun DU, Mijun PENG. Extraction of Chlorogenic Acid From Eucommia ulmoides Leaves by Natural Deep Eutectic Solvent and Its Antioxidant Activity [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 101-109.
[15]	Peiyao WEN, Jiaxin YOU, Yong XU, Junhua ZHANG. Co-production of Xylooligosaccharides and Bacillus subtilis from Poplar [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 1-7.

Research Progress on the Application of Deep Eutectic Solvent in Lignocellulose Pretreatment

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 58

Related Articles 15

Recommended Articles

Metrics

Comments