松香基甲基丙烯酸酯单体的合成和聚合活性分析

›› 2011, Vol. 31 ›› Issue (6): 20-24.

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Synthesis and Characterization of (β-methacryloyloxy) Ethyl Ester of Dehydroabietic Acid

WANG Ji-fu¹, LIN Ming-tao^1,2, WANG Chun-peng^1,2, YU Juan¹, CHU Fu-xiang^1,2

1. Institute of Chemical Industry of Forestry Products,CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.on Forest Chemical Engineering,SFA;Key Lab.of Biomass Energy and Material,Jiangsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry,CAF, Beijing 100091, China

Received:2011-04-19 Revised:1900-01-01 Online:2011-12-30 Published:2011-12-30

Abstract

Abstract: (β-methacryloyloxy)Ethyl ester of dehydroabietic acid (DA-2-HEMA) with a purity of 99.8 % was synthesized by the reaction of dehydroabietic chloride with hydroxyethyl acrylate and characterized by using FT-IR, GC/MS, ¹³C NMR , DSC and GPC. The results showed that (β-methacryloyloxy)ethyl ester of dehydroabietic acid, a type of white crystals with melting point 54.23 ℃, can polymerize in the presence of initiator.The molecular weight of the homopolymer is about 20 000-30 000 g/mol and its glass transition temperature is 73.97 ℃.

Key words: dehydroabietic acid, hydroxyethyl methacrylate, (β-methacryloyloxy)ethyl ester of dehydroabietic acid

CLC Number:

TQ351

WANG Ji-fu;LIN Ming-tao;WANG Chun-peng;YU Juan;CHU Fu-xiang;. Synthesis and Characterization of (β-methacryloyloxy) Ethyl Ester of Dehydroabietic Acid[J]. , 2011, 31(6): 20-24.

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Synthesis and Characterization of (β-methacryloyloxy) Ethyl Ester of Dehydroabietic Acid

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