糠酸制备生物质基2, 5-呋喃二甲酸的研究进展

doi:10.3969/j.issn.0253-2417.2023.02.001

Abstract

Abstract:

As a green bio-based platform chemical, 2, 5-furan dicarboxylic acid(FDCA) was widely used in polyester, plasticizer, fire protection, medicine, etc. At present, according to the distinction of raw materials for the synthesis of FDCA, the synthetic routes of FDCA could be divided into 5-hydroxymethylfurfural(HMF) route, furoic acid route and other raw material routes. Among them, furfural acid could be prepared from the oxidation of bulk bio-based chemical furfural, and the industrial production of furfural made the preparation of FDCA from furfural acid had the potential advantages of green and economical. Based on this, this paper reviews the research status of four methods for preparing FDCA from furoic acid, including: disproportionation, carbonylation, carboxylation and biocatalysis methods. The paper also summarizes a comparative analysis of the advantages and disadvantages of each method and highlights the progress made in their respective research fields. A comparative analysis indicates that the C-H carboxylation method is a gentle and environmentally friendly process, demonstrating significant potential for large-scale production.

Key words: furoic acid, 2, 5-furandicarboxylic acid, biomass, platform compound, carboxylation

CLC Number:

TQ35
TQ251.1

Chun CHANG, Jinsheng WU, Zhiyong CHEN. Research Progress in Preparation of Biomass Based 2, 5-Furan Dicarboxylic Acid from Furoic Acid[J]. Chemistry and Industry of Forest Products, 2023, 43(2): 1-11.

Figures/Tables 11

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反应类型 reaction type	反应物¹⁾ reactant	催化剂 catalyzer	温度/℃ temperature	时间/h time	转化率/% conversion rate	产率²⁾/% yield	文献reference
歧化反应 disproportionation reaction	PF	ZnCl₂	250	3	61	52	[27]
	PF	CdI₂	260	5.5	92	64	[28]
	PF	ZnI₂	260	5.5	48	41	[28]
	PF	ZnCl₂	260	5.5	39	33	[28]
	PF	Ag/SiO₂/CdI₂	200	20	51	264^*	[29]
	PF	Ag/SiO₂	200	20	20	1 203^*	[29]
羰基化反应carbonylation reaction	BrFA	Xantphos/PPh₃/PdCl₂	90	24	>99	>99	[31]
	BrFA	TPPTS/Pd(dba)₂	90	8	>99	98	[32]
	BrFA	Pd(Xantphos)Cl₂/AC	90	16	>99	95	[33]
羧基化反应carboxylation reaction	糠酸铯cesium furoate	Cs₂CO₃	200	5	94	89	[38]
	糠酸铯/糠酸钾cesium furoate/PF	Cs₂CO₃/K₂CO₃	260-285	24	98	89	[40]
	Cu(FC)₂	Cs₂CO₃	220	20	—	99	[41]
	糠酸furoic acid	Cs₂CO₃	220	20	—	76	[41]
	糠酸钠sodium furoate	K₂CO₃/HCOONa	280	6	84	79	[43]
生物催化反应biocatalytic reaction	糠酸furoic acid	HmfF	50	8	—	4	[50]

合成途径 synthetic route	原料来源 material source	反应介质 reaction medium	转化路线特点 characteristic of conversion path	副产物 by-product	工业化实现程度 implementation of industrialization	经济性 economy
歧化法 disproportionation	广泛 abroad	固相solid, 熔融相molten	歧化 disproportionation	较多 more	难 difficult	成本较高 high cost
羰基化法 carbonylation	较少 less	有机相organic, 水相aqueous	C—Br羰基化 carbonylation	较少 less	难 difficult	成本较高 high cost
羧基化法 barboxylation	广泛 abroad	固相solid, 熔融相molten	C—H羧基化 carboxylation	较少 less	难 difficult	成本较低 low cost
生物催化法 biocatalysis	较少 less	液相 liquid	可逆(脱)羧 reversible(de) carboxylation	较少 less	难 difficult	成本较高 high cost

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Research Progress in Preparation of Biomass Based 2, 5-Furan Dicarboxylic Acid from Furoic Acid

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