生物基炭材料在印染废水深度处理中的应用研究进展

doi:10.3969/j.issn.0253-2417.2023.05.019

摘要/Abstract

摘要：

首先总结了生物基炭材料的吸附机理, 并根据作用机理去延伸分析生物基炭原料的选取，以及生物基炭的制备和表面改性方法。综合讨论了炭材料孔道结构、表面官能团等内在因素，以及初始浓度、吸附剂用量、吸附时间、溶液pH值、温度等外在因素对吸附性能的影响, 此外, 对吸附热力学、吸附等温线和吸附动力学等吸附特性展开分析。最后, 总结了生物基炭材料实际应用存在的问题以及未来多样化发展方向, 以期对生物基炭材料在印染废水高效处理中的应用提供参考和借鉴。

关键词: 生物质, 炭材料, 印染废水, 吸附

Abstract:

Firstly, the decontamination mechanism of biomass-based carbon materials was summarized, and the selection, preparation and surface modification methods of biomass raw materials were analyzed according to the mechanism. The effects of internal factors, including pore structure and surface functional groups, and external factors such as initial concentration, adsorbent dosage, contact time, solution pH and temperature on the adsorption performance were discussed. In addition, the adsorption characteristics such as adsorption thermodynamics, adsorption isotherm and adsorption kinetics were analyzed. Finally, the problems existed in the practical application of biomass-based carbon materials and the diverse development directions in the future were summarized, hoping to provide reference for the application of biomass based carbon materials in the high-efficiency treatment of dying wastewater.

Key words: biomass, carbon materials, dyeing wastewater, adsorption

中图分类号:

TQ35
X52

贾爽, 黄美娟, 张博, 卫智毅, 程辉, 李守柱. 生物基炭材料在印染废水深度处理中的应用研究进展[J]. 林产化学与工业, 2023, 43(5): 145-156.

Shuang JIA, Meijuan HUANG, Bo ZHANG, Zhiyi WEI, Hui CHENG, Shouzhu LI. Research Progress of Biomass Based Carbon Materials in the Treatment of Dyeing Wastewater[J]. Chemistry and Industry of Forest Products, 2023, 43(5): 145-156.

图/表 5

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原料 feedstock	染料 dye	活化方式 activation method	S_BET/(m²·g^-1)	吸附容量/(mg·g^-1) adsorption capacity	参考文献 reference
木麻黄casuarina quisetifolia	亚甲基蓝methylene blue	—	—	19.13	[49]
含笑叶magnoliaceae leave	亚甲基蓝methylene blue	—	9.0	238.1	[46]
海草seaweed	亚甲基蓝methylene blue	800 ℃，热解pyrolysis	926.39	512.67	[47]
酒糟废弃物vinasse waste	亚甲基蓝methylene blue	900 ℃，CO₂	80	161	[50]
轮胎废弃物tire waste	亚甲基蓝methylene blue	1 000 ℃，CO₂	237	102	[51]
肉桂豆荚 cassia bakeriana seed pods	刚果红congo red	700 ℃，CO₂	287.6	300	[52]
肉桂豆荚 cassia bakeriana seed pods	刚果红congo red	700 ℃，H₃PO₄	556.6	250	[52]
芥末皮mustard husk	亚甲基蓝methylene blue	738 ℃，KOH	1 187.82	320.53	[53]
扁豆加工剩余物 lentil processing waste	甲基橙methyl orange 亚甲基蓝methylene blue	800 ℃，K₂CO₃	1 875	476 625	[48]
爆米花popcorn	罗明丹B rhodamine B	650 ℃，NaOH	3 291.01	7 765	[54]
胡桃木壳walnut shell	亚甲基蓝methylene blue	800 ℃，ZnCl₂	1 662	314	[55]

吸附剂 adsorbent	快速吸附阶段所需时间/min time required for rapid adsorption stage	参考文献 reference
软木基多孔炭cork-based porous carbon	5	[67]
表面石墨化多孔炭surface graphenization of porous carbon	6	[68]
软木基多孔炭cork-based porous carbon	10	[26]
氯化锌活化咖啡壳ZnCl₂ activated coconut	20	[69]
爆米花基多孔炭popcorn-based porous carbon	45	[54]
氮掺杂食用菌基多孔炭Edible fungus slag derived nitrogen-doped porous carbon	60	[60]
酒糟废弃物多孔炭vinasse waste based porous carbon	100	[27]
咖啡壳水热炭吸附剂coffee husk hydrochar adsorbent	250	[70]
氯化锌活化山竹皮ZnCl₂ activated mangosteen peel	300	[64]

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